High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site

Daniel Streich; Yeni Astuti; Michele Orlandi; Lennart Schwartz; Reiner Lomoth; Leif Hammarström; Sascha Ott

doi:10.1002/chem.200902489

High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site

Daniel Streich, Yeni Astuti, Michele Orlandi, Lennart Schwartz, Reiner Lomoth, Leif Hammarström, Sascha Ott

Uppsala University

Research output: Contribution to journal › Article

167 Citations (Scopus)

Abstract

"Chemical Equation Presented" Lifting the diiron curtain: 200 equivalents of H₂ per catalyst at a maximum turnover rate of 3.7 H₂ per minute can be obtained in a light-driven proton reduction process in near-neutral H₂O/ DMF (pH 5.5) by using an [FeFe]hydrogenase active-site model complex as the catalyst (see scheme).

Original language	English
Pages (from-to)	60-63
Number of pages	4
Journal	Chemistry - A European Journal
Volume	16
Issue number	1
DOIs	https://doi.org/10.1002/chem.200902489
Publication status	Published - Jan 4 2010

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Keywords

Homogeneous catalysis
Hydrogen
Hydrogenase models
Iron
Photochemistry

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Cite this

Streich, D., Astuti, Y., Orlandi, M., Schwartz, L., Lomoth, R., Hammarström, L., & Ott, S. (2010). High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site. Chemistry - A European Journal, 16(1), 60-63. https://doi.org/10.1002/chem.200902489

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10.1002/chem.200902489