High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site

Daniel Streich, Yeni Astuti, Michele Orlandi, Lennart Schwartz, Reiner Lomoth, Leif Hammarström, Sascha Ott

Research output: Contribution to journal › Article

164 Citations (Scopus)

Abstract

"Chemical Equation Presented" Lifting the diiron curtain: 200 equivalents of H2 per catalyst at a maximum turnover rate of 3.7 H2 per minute can be obtained in a light-driven proton reduction process in near-neutral H2O/ DMF (pH 5.5) by using an [FeFe]hydrogenase active-site model complex as the catalyst (see scheme).

Original languageEnglish
Pages (from-to)60-63
Number of pages4
JournalChemistry - A European Journal
Volume16
Issue number1
DOIs
Publication statusPublished - Jan 4 2010

Fingerprint

Hydrogenase
Hydrogen production
Catalysts
Protons

Keywords

  • Homogeneous catalysis
  • Hydrogen
  • Hydrogenase models
  • Iron
  • Photochemistry

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site. / Streich, Daniel; Astuti, Yeni; Orlandi, Michele; Schwartz, Lennart; Lomoth, Reiner; Hammarström, Leif; Ott, Sascha.

In: Chemistry - A European Journal, Vol. 16, No. 1, 04.01.2010, p. 60-63.

Research output: Contribution to journal › Article

Streich, D, Astuti, Y, Orlandi, M, Schwartz, L, Lomoth, R, Hammarström, L & Ott, S 2010, 'High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site', Chemistry - A European Journal, vol. 16, no. 1, pp. 60-63. https://doi.org/10.1002/chem.200902489
Streich D, Astuti Y, Orlandi M, Schwartz L, Lomoth R, Hammarström L et al. High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site. Chemistry - A European Journal. 2010 Jan 4;16(1):60-63. https://doi.org/10.1002/chem.200902489
Streich, Daniel ; Astuti, Yeni ; Orlandi, Michele ; Schwartz, Lennart ; Lomoth, Reiner ; Hammarström, Leif ; Ott, Sascha. / High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site. In: Chemistry - A European Journal. 2010 ; Vol. 16, No. 1. pp. 60-63.
@article{81e3bb1188ab40c09484d4926a1b0acc,
title = "High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site",
abstract = "{"}Chemical Equation Presented{"} Lifting the diiron curtain: 200 equivalents of H2 per catalyst at a maximum turnover rate of 3.7 H2 per minute can be obtained in a light-driven proton reduction process in near-neutral H2O/ DMF (pH 5.5) by using an [FeFe]hydrogenase active-site model complex as the catalyst (see scheme).",
keywords = "Homogeneous catalysis, Hydrogen, Hydrogenase models, Iron, Photochemistry",
author = "Daniel Streich and Yeni Astuti and Michele Orlandi and Lennart Schwartz and Reiner Lomoth and Leif Hammarstr{\"o}m and Sascha Ott",
year = "2010",
month = "1",
day = "4",
doi = "10.1002/chem.200902489",
language = "English",
volume = "16",
pages = "60--63",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "1",

}

TY - JOUR

T1 - High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site

AU - Streich, Daniel

AU - Astuti, Yeni

AU - Orlandi, Michele

AU - Schwartz, Lennart

AU - Lomoth, Reiner

AU - Hammarström, Leif

AU - Ott, Sascha

PY - 2010/1/4

Y1 - 2010/1/4

N2 - "Chemical Equation Presented" Lifting the diiron curtain: 200 equivalents of H2 per catalyst at a maximum turnover rate of 3.7 H2 per minute can be obtained in a light-driven proton reduction process in near-neutral H2O/ DMF (pH 5.5) by using an [FeFe]hydrogenase active-site model complex as the catalyst (see scheme).

AB - "Chemical Equation Presented" Lifting the diiron curtain: 200 equivalents of H2 per catalyst at a maximum turnover rate of 3.7 H2 per minute can be obtained in a light-driven proton reduction process in near-neutral H2O/ DMF (pH 5.5) by using an [FeFe]hydrogenase active-site model complex as the catalyst (see scheme).

KW - Homogeneous catalysis

KW - Hydrogen

KW - Hydrogenase models

KW - Iron

KW - Photochemistry

UR - http://www.scopus.com/inward/record.url?scp=73949132429&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=73949132429&partnerID=8YFLogxK

U2 - 10.1002/chem.200902489

DO - 10.1002/chem.200902489

M3 - Article

C2 - 19938018

AN - SCOPUS:73949132429

VL - 16

SP - 60

EP - 63

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 1

ER -

Access to Document