High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site

Daniel Streich, Yeni Astuti, Michele Orlandi, Lennart Schwartz, Reiner Lomoth, Leif Hammarström, Sascha Ott

Research output: Contribution to journalArticle

163 Citations (Scopus)

Abstract

"Chemical Equation Presented" Lifting the diiron curtain: 200 equivalents of H2 per catalyst at a maximum turnover rate of 3.7 H2 per minute can be obtained in a light-driven proton reduction process in near-neutral H2O/ DMF (pH 5.5) by using an [FeFe]hydrogenase active-site model complex as the catalyst (see scheme).

Original languageEnglish
Pages (from-to)60-63
Number of pages4
JournalChemistry - A European Journal
Volume16
Issue number1
DOIs
Publication statusPublished - Jan 4 2010

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Hydrogenase
Hydrogen production
Catalysts
Protons

Keywords

  • Homogeneous catalysis
  • Hydrogen
  • Hydrogenase models
  • Iron
  • Photochemistry

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site. / Streich, Daniel; Astuti, Yeni; Orlandi, Michele; Schwartz, Lennart; Lomoth, Reiner; Hammarström, Leif; Ott, Sascha.

In: Chemistry - A European Journal, Vol. 16, No. 1, 04.01.2010, p. 60-63.

Research output: Contribution to journalArticle

Streich, Daniel ; Astuti, Yeni ; Orlandi, Michele ; Schwartz, Lennart ; Lomoth, Reiner ; Hammarström, Leif ; Ott, Sascha. / High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site. In: Chemistry - A European Journal. 2010 ; Vol. 16, No. 1. pp. 60-63.
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