Abstract
"Chemical Equation Presented" Lifting the diiron curtain: 200 equivalents of H2 per catalyst at a maximum turnover rate of 3.7 H2 per minute can be obtained in a light-driven proton reduction process in near-neutral H2O/ DMF (pH 5.5) by using an [FeFe]hydrogenase active-site model complex as the catalyst (see scheme).
| Original language | English |
|---|---|
| Pages (from-to) | 60-63 |
| Number of pages | 4 |
| Journal | Chemistry - A European Journal |
| Volume | 16 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 4 2010 |
Keywords
- Homogeneous catalysis
- Hydrogen
- Hydrogenase models
- Iron
- Photochemistry
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
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Cite this
Streich, D., Astuti, Y., Orlandi, M., Schwartz, L., Lomoth, R., Hammarström, L., & Ott, S. (2010). High-turnover photochemical hydrogen production catalyzed by a model complex of the [FeFe]-hydrogenase active site. Chemistry - A European Journal, 16(1), 60-63. https://doi.org/10.1002/chem.200902489