Abstract
"Chemical Equation Presented" Lifting the diiron curtain: 200 equivalents of H2 per catalyst at a maximum turnover rate of 3.7 H2 per minute can be obtained in a light-driven proton reduction process in near-neutral H2O/ DMF (pH 5.5) by using an [FeFe]hydrogenase active-site model complex as the catalyst (see scheme).
Original language | English |
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Pages (from-to) | 60-63 |
Number of pages | 4 |
Journal | Chemistry - A European Journal |
Volume | 16 |
Issue number | 1 |
DOIs | |
Publication status | Published - Jan 4 2010 |
Keywords
- Homogeneous catalysis
- Hydrogen
- Hydrogenase models
- Iron
- Photochemistry
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry