TY - JOUR
T1 - High yields of piperylene in the transfer dehydrogenation of pentane catalyzed by pincer-ligated iridium complexes
AU - Kumar, Akshai
AU - Hackenberg, Jason D.
AU - Zhuo, Gao
AU - Steffens, Andrew M.
AU - Mironov, Oleg
AU - Saxton, Robert J.
AU - Goldman, Alan S
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Conjugated dienes are desirable reagents for several important applications. We report that sterically uncrowded PCP-pincer iridium complexes, including precursors of (i Pr4PCP)Ir and (Me2tBu2PCP)Ir, catalyze the transfer dehydrogenation of pentane, using high concentrations of t‐butylethylene (TBE) as hydrogen acceptor, to give high yields of 1,3-pentadiene (piperylene). Piperylene yields are ca. 100-fold greater than those obtained with the more widely used di(t‐butyl)phosphino substituted pincer iridium catalysts. This represents, to our knowledge, the first reported high-yield synthesis of dienes via the dehydrogenation of n-alkane using molecular catalysts. To our knowledge, this is the first reported high-yield synthesis of dienes achieved via the dehydrogenation of n-alkane using molecular catalysts.
AB - Conjugated dienes are desirable reagents for several important applications. We report that sterically uncrowded PCP-pincer iridium complexes, including precursors of (i Pr4PCP)Ir and (Me2tBu2PCP)Ir, catalyze the transfer dehydrogenation of pentane, using high concentrations of t‐butylethylene (TBE) as hydrogen acceptor, to give high yields of 1,3-pentadiene (piperylene). Piperylene yields are ca. 100-fold greater than those obtained with the more widely used di(t‐butyl)phosphino substituted pincer iridium catalysts. This represents, to our knowledge, the first reported high-yield synthesis of dienes via the dehydrogenation of n-alkane using molecular catalysts. To our knowledge, this is the first reported high-yield synthesis of dienes achieved via the dehydrogenation of n-alkane using molecular catalysts.
KW - Alkane dehydrogenation
KW - Catalytic alkane conversion
KW - C[sbnd]H bond activation
KW - Dienes
KW - Pincer-Iridium complexes
UR - http://www.scopus.com/inward/record.url?scp=85003520628&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85003520628&partnerID=8YFLogxK
U2 - 10.1016/j.molcata.2016.10.019
DO - 10.1016/j.molcata.2016.10.019
M3 - Article
AN - SCOPUS:85003520628
VL - 426
SP - 368
EP - 375
JO - Journal of Molecular Catalysis A: Chemical
JF - Journal of Molecular Catalysis A: Chemical
SN - 1381-1169
ER -