Highly active and robust Cp* iridium complexes for catalytic water oxidation

Jonathan F. Hull; David Balcells; James D. Blakemore; Christopher D. Incarvito; Odile Eisenstein; Gary W. Brudvig; Robert H. Crabtree

doi:10.1021/ja901270f

Highly active and robust Cp* iridium complexes for catalytic water oxidation

Jonathan F. Hull, David Balcells, James D. Blakemore, Christopher D. Incarvito, Odile Eisenstein, Gary W. Brudvig, Robert H. Crabtree

Yale University

Research output: Contribution to journal › Article

448 Citations (Scopus)

Abstract

(Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

Original language	English
Pages (from-to)	8730-8731
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	25
DOIs	https://doi.org/10.1021/ja901270f
Publication status	Published - Jul 1 2009

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja901270f

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Hull, J. F., Balcells, D., Blakemore, J. D., Incarvito, C. D., Eisenstein, O., Brudvig, G. W., & Crabtree, R. H. (2009). Highly active and robust Cp* iridium complexes for catalytic water oxidation. Journal of the American Chemical Society, 131(25), 8730-8731. https://doi.org/10.1021/ja901270f

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abstract = "(Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.",

author = "Hull, {Jonathan F.} and David Balcells and Blakemore, {James D.} and Incarvito, {Christopher D.} and Odile Eisenstein and Brudvig, {Gary W.} and Crabtree, {Robert H.}",

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AU - Brudvig, Gary W.

AU - Crabtree, Robert H.

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