Highly active and robust Cp* iridium complexes for catalytic water oxidation

Jonathan F. Hull, David Balcells, James D. Blakemore, Christopher D. Incarvito, Odile Eisenstein, Gary W Brudvig, Robert H. Crabtree

Research output: Contribution to journalArticle

434 Citations (Scopus)

Abstract

(Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

Original languageEnglish
Pages (from-to)8730-8731
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number25
DOIs
Publication statusPublished - Jul 1 2009

    Fingerprint

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Hull, J. F., Balcells, D., Blakemore, J. D., Incarvito, C. D., Eisenstein, O., Brudvig, G. W., & Crabtree, R. H. (2009). Highly active and robust Cp* iridium complexes for catalytic water oxidation. Journal of the American Chemical Society, 131(25), 8730-8731. https://doi.org/10.1021/ja901270f