Highly active and robust Cp* iridium complexes for catalytic water oxidation

Jonathan F. Hull; David Balcells; James D. Blakemore; Christopher D. Incarvito; Odile Eisenstein; Gary W. Brudvig; Robert H. Crabtree

doi:10.1021/ja901270f

Highly active and robust Cp* iridium complexes for catalytic water oxidation

Jonathan F. Hull, David Balcells, James D. Blakemore, Christopher D. Incarvito, Odile Eisenstein, Gary W. Brudvig, Robert H. Crabtree

Yale University

Research output: Contribution to journal › Article › peer-review

457 Citations (Scopus)

Abstract

(Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

Original language	English
Pages (from-to)	8730-8731
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	25
DOIs	https://doi.org/10.1021/ja901270f
Publication status	Published - Jul 1 2009

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja901270f

Fingerprint Dive into the research topics of 'Highly active and robust Cp* iridium complexes for catalytic water oxidation'. Together they form a unique fingerprint.

Cite this

Highly active and robust Cp* iridium complexes for catalytic water oxidation. / Hull, Jonathan F.; Balcells, David; Blakemore, James D.; Incarvito, Christopher D.; Eisenstein, Odile; Brudvig, Gary W.; Crabtree, Robert H.

In: Journal of the American Chemical Society, Vol. 131, No. 25, 01.07.2009, p. 8730-8731.

Research output: Contribution to journal › Article › peer-review

@article{cafbafb15bad4ff8b914d5709461ddf1,

title = "Highly active and robust Cp* iridium complexes for catalytic water oxidation",

abstract = "(Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.",

author = "Hull, {Jonathan F.} and David Balcells and Blakemore, {James D.} and Incarvito, {Christopher D.} and Odile Eisenstein and Brudvig, {Gary W.} and Crabtree, {Robert H.}",

year = "2009",

month = jul,

day = "1",

doi = "10.1021/ja901270f",

language = "English",

volume = "131",

pages = "8730--8731",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "25",

}

TY - JOUR

T1 - Highly active and robust Cp* iridium complexes for catalytic water oxidation

AU - Hull, Jonathan F.

AU - Balcells, David

AU - Blakemore, James D.

AU - Incarvito, Christopher D.

AU - Eisenstein, Odile

AU - Brudvig, Gary W.

AU - Crabtree, Robert H.

PY - 2009/7/1

Y1 - 2009/7/1

N2 - (Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

AB - (Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

UR - http://www.scopus.com/inward/record.url?scp=67649586417&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67649586417&partnerID=8YFLogxK

U2 - 10.1021/ja901270f

DO - 10.1021/ja901270f

M3 - Article

C2 - 19496565

AN - SCOPUS:67649586417

VL - 131

SP - 8730

EP - 8731

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 25

ER -