Highly active and robust Cp* iridium complexes for catalytic water oxidation

Jonathan F. Hull, David Balcells, James D. Blakemore, Christopher D. Incarvito, Odile Eisenstein, Gary W Brudvig, Robert H. Crabtree

Research output: Contribution to journal › Article

433 Citations (Scopus)

Abstract

(Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

Original languageEnglish
Pages (from-to)8730-8731
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number25
DOIs
Publication statusPublished - Jul 1 2009

Fingerprint

Iridium
Discrete Fourier transforms
Oxidation
Catalysts
Water

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Hull, J. F., Balcells, D., Blakemore, J. D., Incarvito, C. D., Eisenstein, O., Brudvig, G. W., & Crabtree, R. H. (2009). Highly active and robust Cp* iridium complexes for catalytic water oxidation. Journal of the American Chemical Society, 131(25), 8730-8731. https://doi.org/10.1021/ja901270f

Highly active and robust Cp* iridium complexes for catalytic water oxidation. / Hull, Jonathan F.; Balcells, David; Blakemore, James D.; Incarvito, Christopher D.; Eisenstein, Odile; Brudvig, Gary W; Crabtree, Robert H.

In: Journal of the American Chemical Society, Vol. 131, No. 25, 01.07.2009, p. 8730-8731.

Research output: Contribution to journal › Article

Hull, JF, Balcells, D, Blakemore, JD, Incarvito, CD, Eisenstein, O, Brudvig, GW & Crabtree, RH 2009, 'Highly active and robust Cp* iridium complexes for catalytic water oxidation', Journal of the American Chemical Society, vol. 131, no. 25, pp. 8730-8731. https://doi.org/10.1021/ja901270f
Hull JF, Balcells D, Blakemore JD, Incarvito CD, Eisenstein O, Brudvig GW et al. Highly active and robust Cp* iridium complexes for catalytic water oxidation. Journal of the American Chemical Society. 2009 Jul 1;131(25):8730-8731. https://doi.org/10.1021/ja901270f
Hull, Jonathan F. ; Balcells, David ; Blakemore, James D. ; Incarvito, Christopher D. ; Eisenstein, Odile ; Brudvig, Gary W ; Crabtree, Robert H. / Highly active and robust Cp* iridium complexes for catalytic water oxidation. In: Journal of the American Chemical Society. 2009 ; Vol. 131, No. 25. pp. 8730-8731.
@article{cafbafb15bad4ff8b914d5709461ddf1,
title = "Highly active and robust Cp* iridium complexes for catalytic water oxidation",
abstract = "(Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.",
author = "Hull, {Jonathan F.} and David Balcells and Blakemore, {James D.} and Incarvito, {Christopher D.} and Odile Eisenstein and Brudvig, {Gary W} and Crabtree, {Robert H.}",
year = "2009",
month = "7",
day = "1",
doi = "10.1021/ja901270f",
language = "English",
volume = "131",
pages = "8730--8731",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "25",

}

TY - JOUR

T1 - Highly active and robust Cp* iridium complexes for catalytic water oxidation

AU - Hull, Jonathan F.

AU - Balcells, David

AU - Blakemore, James D.

AU - Incarvito, Christopher D.

AU - Eisenstein, Odile

AU - Brudvig, Gary W

AU - Crabtree, Robert H.

PY - 2009/7/1

Y1 - 2009/7/1

N2 - (Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

AB - (Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

UR - http://www.scopus.com/inward/record.url?scp=67649586417&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67649586417&partnerID=8YFLogxK

U2 - 10.1021/ja901270f

DO - 10.1021/ja901270f

M3 - Article

C2 - 19496565

AN - SCOPUS:67649586417

VL - 131

SP - 8730

EP - 8731

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 25

ER -

Access to Document