Highly active and robust Cp* iridium complexes for catalytic water oxidation

Jonathan F. Hull, David Balcells, James D. Blakemore, Christopher D. Incarvito, Odile Eisenstein, Gary W Brudvig, Robert H. Crabtree

Research output: Contribution to journalArticle

433 Citations (Scopus)

Abstract

(Chemical Equation Presented) A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

Original languageEnglish
Pages (from-to)8730-8731
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number25
DOIs
Publication statusPublished - Jul 1 2009

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Iridium
Discrete Fourier transforms
Oxidation
Catalysts
Water

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Hull, J. F., Balcells, D., Blakemore, J. D., Incarvito, C. D., Eisenstein, O., Brudvig, G. W., & Crabtree, R. H. (2009). Highly active and robust Cp* iridium complexes for catalytic water oxidation. Journal of the American Chemical Society, 131(25), 8730-8731. https://doi.org/10.1021/ja901270f

Highly active and robust Cp* iridium complexes for catalytic water oxidation. / Hull, Jonathan F.; Balcells, David; Blakemore, James D.; Incarvito, Christopher D.; Eisenstein, Odile; Brudvig, Gary W; Crabtree, Robert H.

In: Journal of the American Chemical Society, Vol. 131, No. 25, 01.07.2009, p. 8730-8731.

Research output: Contribution to journalArticle

Hull, JF, Balcells, D, Blakemore, JD, Incarvito, CD, Eisenstein, O, Brudvig, GW & Crabtree, RH 2009, 'Highly active and robust Cp* iridium complexes for catalytic water oxidation', Journal of the American Chemical Society, vol. 131, no. 25, pp. 8730-8731. https://doi.org/10.1021/ja901270f
Hull, Jonathan F. ; Balcells, David ; Blakemore, James D. ; Incarvito, Christopher D. ; Eisenstein, Odile ; Brudvig, Gary W ; Crabtree, Robert H. / Highly active and robust Cp* iridium complexes for catalytic water oxidation. In: Journal of the American Chemical Society. 2009 ; Vol. 131, No. 25. pp. 8730-8731.
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