Abstract
Developing nonprecious hydrogen evolution electrocatalysts that can work well at large current densities (e.g., at 1000 mA/cm2: a value that is relevant for practical, large-scale applications) is of great importance for realizing a viable water-splitting technology. Herein we present a combined theoretical and experimental study that leads to the identification of α-phase molybdenum diboride (α-MoB2) comprising borophene subunits as a noble metal-free, superefficient electrocatalyst for the hydrogen evolution reaction (HER). Our theoretical finding indicates, unlike the surfaces of Pt- and MoS2-based catalysts, those of α-MoB2 can maintain high catalytic activity for HER even at very high hydrogen coverage and attain a high density of efficient catalytic active sites. Experiments confirm α-MoB2 can deliver large current densities in the order of 1000 mA/cm2, and also has excellent catalytic stability during HER. The theoretical and experimental results show α-MoB2's catalytic activity, especially at large current densities, is due to its high conductivity, large density of efficient catalytic active sites and good mass transport property.
| Original language | English |
|---|---|
| Pages (from-to) | 12370-12373 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 139 |
| Issue number | 36 |
| DOIs | |
| Publication status | Published - Jan 1 2017 |
Fingerprint
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Highly Active, Nonprecious Electrocatalyst Comprising Borophene Subunits for the Hydrogen Evolution Reaction. / Chen, Yanli; Yu, Guangtao; Chen, Wei; Liu, Yipu; Li, Guo Dong; Zhu, Pinwen; Tao, Qiang; Li, Qiuju; Liu, Jingwei; Shen, Xiaopeng; Li, Hui; Huang, Xuri; Wang, Dejun; Asefa, Teddy; Zou, Xiaoxin.
In: Journal of the American Chemical Society, Vol. 139, No. 36, 01.01.2017, p. 12370-12373.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Highly Active, Nonprecious Electrocatalyst Comprising Borophene Subunits for the Hydrogen Evolution Reaction
AU - Chen, Yanli
AU - Yu, Guangtao
AU - Chen, Wei
AU - Liu, Yipu
AU - Li, Guo Dong
AU - Zhu, Pinwen
AU - Tao, Qiang
AU - Li, Qiuju
AU - Liu, Jingwei
AU - Shen, Xiaopeng
AU - Li, Hui
AU - Huang, Xuri
AU - Wang, Dejun
AU - Asefa, Teddy
AU - Zou, Xiaoxin
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Developing nonprecious hydrogen evolution electrocatalysts that can work well at large current densities (e.g., at 1000 mA/cm2: a value that is relevant for practical, large-scale applications) is of great importance for realizing a viable water-splitting technology. Herein we present a combined theoretical and experimental study that leads to the identification of α-phase molybdenum diboride (α-MoB2) comprising borophene subunits as a noble metal-free, superefficient electrocatalyst for the hydrogen evolution reaction (HER). Our theoretical finding indicates, unlike the surfaces of Pt- and MoS2-based catalysts, those of α-MoB2 can maintain high catalytic activity for HER even at very high hydrogen coverage and attain a high density of efficient catalytic active sites. Experiments confirm α-MoB2 can deliver large current densities in the order of 1000 mA/cm2, and also has excellent catalytic stability during HER. The theoretical and experimental results show α-MoB2's catalytic activity, especially at large current densities, is due to its high conductivity, large density of efficient catalytic active sites and good mass transport property.
AB - Developing nonprecious hydrogen evolution electrocatalysts that can work well at large current densities (e.g., at 1000 mA/cm2: a value that is relevant for practical, large-scale applications) is of great importance for realizing a viable water-splitting technology. Herein we present a combined theoretical and experimental study that leads to the identification of α-phase molybdenum diboride (α-MoB2) comprising borophene subunits as a noble metal-free, superefficient electrocatalyst for the hydrogen evolution reaction (HER). Our theoretical finding indicates, unlike the surfaces of Pt- and MoS2-based catalysts, those of α-MoB2 can maintain high catalytic activity for HER even at very high hydrogen coverage and attain a high density of efficient catalytic active sites. Experiments confirm α-MoB2 can deliver large current densities in the order of 1000 mA/cm2, and also has excellent catalytic stability during HER. The theoretical and experimental results show α-MoB2's catalytic activity, especially at large current densities, is due to its high conductivity, large density of efficient catalytic active sites and good mass transport property.
UR - http://www.scopus.com/inward/record.url?scp=85029482778&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85029482778&partnerID=8YFLogxK
U2 - 10.1021/jacs.7b06337
DO - 10.1021/jacs.7b06337
M3 - Article
AN - SCOPUS:85029482778
VL - 139
SP - 12370
EP - 12373
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 36
ER -