Highly active Pd(II) cyclometallated imine catalysts for the Heck reaction

Manuela Ohff; Andreas Ohff; David Milstein

doi:10.1039/a809883b

Highly active Pd(II) cyclometallated imine catalysts for the Heck reaction

Manuela Ohff, Andreas Ohff, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

236 Citations (Scopus)

Abstract

The new cyclopalladated, phosphine-free imine complexes 1-3 are exceptional catalysts for the Heck arylation, leading to more than a million turnovers in some cases; the catalysts are very thermally and air stable and are recovered unchanged after the catalysis.

Original language	English
Pages (from-to)	357-358
Number of pages	2
Journal	Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/a809883b
Publication status	Published - Feb 21 1999

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Highly active Pd(II) cyclometallated imine catalysts for the Heck reaction",

abstract = "The new cyclopalladated, phosphine-free imine complexes 1-3 are exceptional catalysts for the Heck arylation, leading to more than a million turnovers in some cases; the catalysts are very thermally and air stable and are recovered unchanged after the catalysis.",

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