TY - JOUR
T1 - Highly selective CO2 capture by a flexible microporous metal-organic framework (MMOF) material
AU - Wu, Haohan
AU - Reali, Randall S.
AU - Smith, David A.
AU - Trachtenberg, Michael C.
AU - Li, Jing
PY - 2010/12/17
Y1 - 2010/12/17
N2 - Caught in a CO2 trap: A highly flexible microporous metal-organic framework material exhibits a remarkable ability to capture and separate carbon dioxide from other small gases, such as N2, H 2, CH4, CO, and O2, with separation ratios of 294, 190, 257, and 441 for CO2/N2, CO2/H 2, CO2/CH4, and CO2/CO, respectively, at 0.16 atm and 25 °C, and 768 for CO2/O 2 at 0.2 atm and 25 °C.
AB - Caught in a CO2 trap: A highly flexible microporous metal-organic framework material exhibits a remarkable ability to capture and separate carbon dioxide from other small gases, such as N2, H 2, CH4, CO, and O2, with separation ratios of 294, 190, 257, and 441 for CO2/N2, CO2/H 2, CO2/CH4, and CO2/CO, respectively, at 0.16 atm and 25 °C, and 768 for CO2/O 2 at 0.2 atm and 25 °C.
KW - adsorption
KW - carbon dioxide
KW - carbon dioxide fixation
KW - metal-organic frameworks
KW - microporous materials
KW - separation selectivity
UR - http://www.scopus.com/inward/record.url?scp=78650290767&partnerID=8YFLogxK
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U2 - 10.1002/chem.201002683
DO - 10.1002/chem.201002683
M3 - Article
C2 - 21108262
AN - SCOPUS:78650290767
VL - 16
SP - 13951
EP - 13954
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 47
ER -