Highly selective CO2 capture by a flexible microporous metal-organic framework (MMOF) material

Haohan Wu; Randall S. Reali; David A. Smith; Michael C. Trachtenberg; Jing Li

doi:10.1002/chem.201002683

Highly selective CO₂ capture by a flexible microporous metal-organic framework (MMOF) material

Haohan Wu, Randall S. Reali, David A. Smith, Michael C. Trachtenberg, Jing Li

Rutgers University

Research output: Contribution to journal › Article › peer-review

127 Citations (Scopus)

Abstract

Caught in a CO₂ trap: A highly flexible microporous metal-organic framework material exhibits a remarkable ability to capture and separate carbon dioxide from other small gases, such as N₂, H ₂, CH₄, CO, and O₂, with separation ratios of 294, 190, 257, and 441 for CO₂/N₂, CO₂/H ₂, CO₂/CH₄, and CO₂/CO, respectively, at 0.16 atm and 25 °C, and 768 for CO₂/O ₂ at 0.2 atm and 25 °C.

Original language	English
Pages (from-to)	13951-13954
Number of pages	4
Journal	Chemistry - A European Journal
Volume	16
Issue number	47
DOIs	https://doi.org/10.1002/chem.201002683
Publication status	Published - Dec 17 2010

Keywords

adsorption
carbon dioxide
carbon dioxide fixation
metal-organic frameworks
microporous materials
separation selectivity

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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title = "Highly selective CO2 capture by a flexible microporous metal-organic framework (MMOF) material",

abstract = "Caught in a CO2 trap: A highly flexible microporous metal-organic framework material exhibits a remarkable ability to capture and separate carbon dioxide from other small gases, such as N2, H 2, CH4, CO, and O2, with separation ratios of 294, 190, 257, and 441 for CO2/N2, CO2/H 2, CO2/CH4, and CO2/CO, respectively, at 0.16 atm and 25 °C, and 768 for CO2/O 2 at 0.2 atm and 25 °C.",

keywords = "adsorption, carbon dioxide, carbon dioxide fixation, metal-organic frameworks, microporous materials, separation selectivity",

author = "Haohan Wu and Reali, {Randall S.} and Smith, {David A.} and Trachtenberg, {Michael C.} and Jing Li",

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T1 - Highly selective CO2 capture by a flexible microporous metal-organic framework (MMOF) material

AU - Wu, Haohan

AU - Reali, Randall S.

AU - Smith, David A.

AU - Trachtenberg, Michael C.

AU - Li, Jing

PY - 2010/12/17

Y1 - 2010/12/17

N2 - Caught in a CO2 trap: A highly flexible microporous metal-organic framework material exhibits a remarkable ability to capture and separate carbon dioxide from other small gases, such as N2, H 2, CH4, CO, and O2, with separation ratios of 294, 190, 257, and 441 for CO2/N2, CO2/H 2, CO2/CH4, and CO2/CO, respectively, at 0.16 atm and 25 °C, and 768 for CO2/O 2 at 0.2 atm and 25 °C.

AB - Caught in a CO2 trap: A highly flexible microporous metal-organic framework material exhibits a remarkable ability to capture and separate carbon dioxide from other small gases, such as N2, H 2, CH4, CO, and O2, with separation ratios of 294, 190, 257, and 441 for CO2/N2, CO2/H 2, CO2/CH4, and CO2/CO, respectively, at 0.16 atm and 25 °C, and 768 for CO2/O 2 at 0.2 atm and 25 °C.

KW - adsorption

KW - carbon dioxide

KW - carbon dioxide fixation

KW - metal-organic frameworks

KW - microporous materials

KW - separation selectivity

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