Highly selective CO2 capture by a flexible microporous metal-organic framework (MMOF) material

Haohan Wu; Randall S. Reali; David A. Smith; Michael C. Trachtenberg; Jing Li

doi:10.1002/chem.201002683

Highly selective CO₂ capture by a flexible microporous metal-organic framework (MMOF) material

Haohan Wu, Randall S. Reali, David A. Smith, Michael C. Trachtenberg, Jing Li

Rutgers University

Research output: Contribution to journal › Article

124 Citations (Scopus)

Abstract

Caught in a CO₂ trap: A highly flexible microporous metal-organic framework material exhibits a remarkable ability to capture and separate carbon dioxide from other small gases, such as N₂, H ₂, CH₄, CO, and O₂, with separation ratios of 294, 190, 257, and 441 for CO₂/N₂, CO₂/H ₂, CO₂/CH₄, and CO₂/CO, respectively, at 0.16 atm and 25 °C, and 768 for CO₂/O ₂ at 0.2 atm and 25 °C.

Original language	English
Pages (from-to)	13951-13954
Number of pages	4
Journal	Chemistry - A European Journal
Volume	16
Issue number	47
DOIs	https://doi.org/10.1002/chem.201002683
Publication status	Published - Dec 17 2010

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Keywords

adsorption
carbon dioxide
carbon dioxide fixation
metal-organic frameworks
microporous materials
separation selectivity

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Cite this

Wu, H., Reali, R. S., Smith, D. A., Trachtenberg, M. C., & Li, J. (2010). Highly selective CO₂ capture by a flexible microporous metal-organic framework (MMOF) material. Chemistry - A European Journal, 16(47), 13951-13954. https://doi.org/10.1002/chem.201002683

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abstract = "Caught in a CO2 trap: A highly flexible microporous metal-organic framework material exhibits a remarkable ability to capture and separate carbon dioxide from other small gases, such as N2, H 2, CH4, CO, and O2, with separation ratios of 294, 190, 257, and 441 for CO2/N2, CO2/H 2, CO2/CH4, and CO2/CO, respectively, at 0.16 atm and 25 °C, and 768 for CO2/O 2 at 0.2 atm and 25 °C.",

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AU - Wu, Haohan

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AU - Li, Jing

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AB - Caught in a CO2 trap: A highly flexible microporous metal-organic framework material exhibits a remarkable ability to capture and separate carbon dioxide from other small gases, such as N2, H 2, CH4, CO, and O2, with separation ratios of 294, 190, 257, and 441 for CO2/N2, CO2/H 2, CO2/CH4, and CO2/CO, respectively, at 0.16 atm and 25 °C, and 768 for CO2/O 2 at 0.2 atm and 25 °C.

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KW - carbon dioxide

KW - carbon dioxide fixation

KW - metal-organic frameworks

KW - microporous materials

KW - separation selectivity

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10.1002/chem.201002683