Hole mobility in DNA a tracts

Frederick D. Lewis, Huihe Zhu, Pierre Daublain, Boiko Cohen, Michael R Wasielewski

Research output: Contribution to journalArticle

71 Citations (Scopus)

Abstract

Whole scheme of things: The kinetics and efficiency of photoinduced hole transport across DNA A tracts with 1-7 base pairs have been determined from femtosecond transient absorption spectroscopic data. These values are strongly distance dependent over the first four base pairs, but are relatively insensitive to distance at longer distances. These kinetic results (□, ■) parallel the DNA-strand-cleavage results of Giese et al. (○, Black circle). (Graph Presented).

Original languageEnglish
Pages (from-to)7982-7985
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number47
DOIs
Publication statusPublished - Dec 4 2006

Fingerprint

Hole mobility
DNA
Kinetics

Keywords

  • DNA conjugates
  • Electron transfer
  • Hole hopping
  • Hole injection
  • Hole trapping

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Hole mobility in DNA a tracts. / Lewis, Frederick D.; Zhu, Huihe; Daublain, Pierre; Cohen, Boiko; Wasielewski, Michael R.

In: Angewandte Chemie - International Edition, Vol. 45, No. 47, 04.12.2006, p. 7982-7985.

Research output: Contribution to journalArticle

Lewis, FD, Zhu, H, Daublain, P, Cohen, B & Wasielewski, MR 2006, 'Hole mobility in DNA a tracts', Angewandte Chemie - International Edition, vol. 45, no. 47, pp. 7982-7985. https://doi.org/10.1002/anie.200603455
Lewis, Frederick D. ; Zhu, Huihe ; Daublain, Pierre ; Cohen, Boiko ; Wasielewski, Michael R. / Hole mobility in DNA a tracts. In: Angewandte Chemie - International Edition. 2006 ; Vol. 45, No. 47. pp. 7982-7985.
@article{4305b86e709447378808299ff15ac828,
title = "Hole mobility in DNA a tracts",
abstract = "Whole scheme of things: The kinetics and efficiency of photoinduced hole transport across DNA A tracts with 1-7 base pairs have been determined from femtosecond transient absorption spectroscopic data. These values are strongly distance dependent over the first four base pairs, but are relatively insensitive to distance at longer distances. These kinetic results (□, ■) parallel the DNA-strand-cleavage results of Giese et al. (○, Black circle). (Graph Presented).",
keywords = "DNA conjugates, Electron transfer, Hole hopping, Hole injection, Hole trapping",
author = "Lewis, {Frederick D.} and Huihe Zhu and Pierre Daublain and Boiko Cohen and Wasielewski, {Michael R}",
year = "2006",
month = "12",
day = "4",
doi = "10.1002/anie.200603455",
language = "English",
volume = "45",
pages = "7982--7985",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "47",

}

TY - JOUR

T1 - Hole mobility in DNA a tracts

AU - Lewis, Frederick D.

AU - Zhu, Huihe

AU - Daublain, Pierre

AU - Cohen, Boiko

AU - Wasielewski, Michael R

PY - 2006/12/4

Y1 - 2006/12/4

N2 - Whole scheme of things: The kinetics and efficiency of photoinduced hole transport across DNA A tracts with 1-7 base pairs have been determined from femtosecond transient absorption spectroscopic data. These values are strongly distance dependent over the first four base pairs, but are relatively insensitive to distance at longer distances. These kinetic results (□, ■) parallel the DNA-strand-cleavage results of Giese et al. (○, Black circle). (Graph Presented).

AB - Whole scheme of things: The kinetics and efficiency of photoinduced hole transport across DNA A tracts with 1-7 base pairs have been determined from femtosecond transient absorption spectroscopic data. These values are strongly distance dependent over the first four base pairs, but are relatively insensitive to distance at longer distances. These kinetic results (□, ■) parallel the DNA-strand-cleavage results of Giese et al. (○, Black circle). (Graph Presented).

KW - DNA conjugates

KW - Electron transfer

KW - Hole hopping

KW - Hole injection

KW - Hole trapping

UR - http://www.scopus.com/inward/record.url?scp=33845500080&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33845500080&partnerID=8YFLogxK

U2 - 10.1002/anie.200603455

DO - 10.1002/anie.200603455

M3 - Article

VL - 45

SP - 7982

EP - 7985

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 47

ER -