Homochiral metal-organic coordination networks from l-typtophan

Yu Xie, Ying Yan, Hao Han Wu, Guo Ping Yong, Yong Cui, Zhi Yong Wang, Long Pan, Jing Li, Rong Fan, Rui Peng Li, Yang Chao Tian, Guo Qiang Pan, Liu Si Sheng, Xing Li

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Three homochiral metal-organic coordination networks [Co2(l-Trp)2(Py)6] · Py · (ClO4)2 (1), [Ni(l-Trp)(Py)3] · H2O · ClO4 (2) and [Co2(l-Trp)(INT)2(H2O)2 (ClO4)] (3), all containing natural amino acid l-HTrp (l-typtophan), were hydrothermally synthesized and structurally characterized. The compounds 1 and 2 crystallize in the orthorhombic space group C2221, with a = 10.731(2) Å, b = 19.709(4) Å, c = 27.365(6) Å and Z = 4 for 1 and a = 10.710(10) Å, b = 20.088(18) Å, c = 27.63(3) Å and Z = 8 for 2, respectively. The compound 3 has the monoclinic space group P21, with a = 8.1934(14) Å, b = 13.209(2) Å, c = 12.464(2) Å, β = 104.107(3)° and Z = 2. Both 1 and 2 consist of 1D helical chains. Compound 3 is composed of 2D networks, which further assemble into a 3D supramolecular structure via weak interlayer interactions. The optically pure amino acid l-HTrp plays an important role leading to homochiral structures reported here.

Original languageEnglish
Pages (from-to)1669-1677
Number of pages9
JournalInorganica Chimica Acta
Volume360
Issue number5
DOIs
Publication statusPublished - Apr 1 2007

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amino acids
Amino acids
Metals
metals
Amino Acids
interlayers
interactions
perchlorate
iodonitrotetrazolium

Keywords

  • 2D networks
  • Chiral revulsive
  • Helical chain
  • Homochiral building unit
  • Natural l-typtophan coordination networks

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Xie, Y., Yan, Y., Wu, H. H., Yong, G. P., Cui, Y., Wang, Z. Y., ... Li, X. (2007). Homochiral metal-organic coordination networks from l-typtophan. Inorganica Chimica Acta, 360(5), 1669-1677. https://doi.org/10.1016/j.ica.2006.09.032

Homochiral metal-organic coordination networks from l-typtophan. / Xie, Yu; Yan, Ying; Wu, Hao Han; Yong, Guo Ping; Cui, Yong; Wang, Zhi Yong; Pan, Long; Li, Jing; Fan, Rong; Li, Rui Peng; Tian, Yang Chao; Pan, Guo Qiang; Sheng, Liu Si; Li, Xing.

In: Inorganica Chimica Acta, Vol. 360, No. 5, 01.04.2007, p. 1669-1677.

Research output: Contribution to journalArticle

Xie, Y, Yan, Y, Wu, HH, Yong, GP, Cui, Y, Wang, ZY, Pan, L, Li, J, Fan, R, Li, RP, Tian, YC, Pan, GQ, Sheng, LS & Li, X 2007, 'Homochiral metal-organic coordination networks from l-typtophan', Inorganica Chimica Acta, vol. 360, no. 5, pp. 1669-1677. https://doi.org/10.1016/j.ica.2006.09.032
Xie Y, Yan Y, Wu HH, Yong GP, Cui Y, Wang ZY et al. Homochiral metal-organic coordination networks from l-typtophan. Inorganica Chimica Acta. 2007 Apr 1;360(5):1669-1677. https://doi.org/10.1016/j.ica.2006.09.032
Xie, Yu ; Yan, Ying ; Wu, Hao Han ; Yong, Guo Ping ; Cui, Yong ; Wang, Zhi Yong ; Pan, Long ; Li, Jing ; Fan, Rong ; Li, Rui Peng ; Tian, Yang Chao ; Pan, Guo Qiang ; Sheng, Liu Si ; Li, Xing. / Homochiral metal-organic coordination networks from l-typtophan. In: Inorganica Chimica Acta. 2007 ; Vol. 360, No. 5. pp. 1669-1677.
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abstract = "Three homochiral metal-organic coordination networks [Co2(l-Trp)2(Py)6] · Py · (ClO4)2 (1), [Ni(l-Trp)(Py)3] · H2O · ClO4 (2) and [Co2(l-Trp)(INT)2(H2O)2 (ClO4)] (3), all containing natural amino acid l-HTrp (l-typtophan), were hydrothermally synthesized and structurally characterized. The compounds 1 and 2 crystallize in the orthorhombic space group C2221, with a = 10.731(2) {\AA}, b = 19.709(4) {\AA}, c = 27.365(6) {\AA} and Z = 4 for 1 and a = 10.710(10) {\AA}, b = 20.088(18) {\AA}, c = 27.63(3) {\AA} and Z = 8 for 2, respectively. The compound 3 has the monoclinic space group P21, with a = 8.1934(14) {\AA}, b = 13.209(2) {\AA}, c = 12.464(2) {\AA}, β = 104.107(3)° and Z = 2. Both 1 and 2 consist of 1D helical chains. Compound 3 is composed of 2D networks, which further assemble into a 3D supramolecular structure via weak interlayer interactions. The optically pure amino acid l-HTrp plays an important role leading to homochiral structures reported here.",
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AU - Xie, Yu

AU - Yan, Ying

AU - Wu, Hao Han

AU - Yong, Guo Ping

AU - Cui, Yong

AU - Wang, Zhi Yong

AU - Pan, Long

AU - Li, Jing

AU - Fan, Rong

AU - Li, Rui Peng

AU - Tian, Yang Chao

AU - Pan, Guo Qiang

AU - Sheng, Liu Si

AU - Li, Xing

PY - 2007/4/1

Y1 - 2007/4/1

N2 - Three homochiral metal-organic coordination networks [Co2(l-Trp)2(Py)6] · Py · (ClO4)2 (1), [Ni(l-Trp)(Py)3] · H2O · ClO4 (2) and [Co2(l-Trp)(INT)2(H2O)2 (ClO4)] (3), all containing natural amino acid l-HTrp (l-typtophan), were hydrothermally synthesized and structurally characterized. The compounds 1 and 2 crystallize in the orthorhombic space group C2221, with a = 10.731(2) Å, b = 19.709(4) Å, c = 27.365(6) Å and Z = 4 for 1 and a = 10.710(10) Å, b = 20.088(18) Å, c = 27.63(3) Å and Z = 8 for 2, respectively. The compound 3 has the monoclinic space group P21, with a = 8.1934(14) Å, b = 13.209(2) Å, c = 12.464(2) Å, β = 104.107(3)° and Z = 2. Both 1 and 2 consist of 1D helical chains. Compound 3 is composed of 2D networks, which further assemble into a 3D supramolecular structure via weak interlayer interactions. The optically pure amino acid l-HTrp plays an important role leading to homochiral structures reported here.

AB - Three homochiral metal-organic coordination networks [Co2(l-Trp)2(Py)6] · Py · (ClO4)2 (1), [Ni(l-Trp)(Py)3] · H2O · ClO4 (2) and [Co2(l-Trp)(INT)2(H2O)2 (ClO4)] (3), all containing natural amino acid l-HTrp (l-typtophan), were hydrothermally synthesized and structurally characterized. The compounds 1 and 2 crystallize in the orthorhombic space group C2221, with a = 10.731(2) Å, b = 19.709(4) Å, c = 27.365(6) Å and Z = 4 for 1 and a = 10.710(10) Å, b = 20.088(18) Å, c = 27.63(3) Å and Z = 8 for 2, respectively. The compound 3 has the monoclinic space group P21, with a = 8.1934(14) Å, b = 13.209(2) Å, c = 12.464(2) Å, β = 104.107(3)° and Z = 2. Both 1 and 2 consist of 1D helical chains. Compound 3 is composed of 2D networks, which further assemble into a 3D supramolecular structure via weak interlayer interactions. The optically pure amino acid l-HTrp plays an important role leading to homochiral structures reported here.

KW - 2D networks

KW - Chiral revulsive

KW - Helical chain

KW - Homochiral building unit

KW - Natural l-typtophan coordination networks

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