Homochiral metal-organic coordination networks from l-typtophan

Yu Xie, Ying Yan, Hao Han Wu, Guo Ping Yong, Yong Cui, Zhi Yong Wang, Long Pan, Jing Li, Rong Fan, Rui Peng Li, Yang Chao Tian, Guo Qiang Pan, Liu Si Sheng, Xing Li

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Three homochiral metal-organic coordination networks [Co2(l-Trp)2(Py)6] · Py · (ClO4)2 (1), [Ni(l-Trp)(Py)3] · H2O · ClO4 (2) and [Co2(l-Trp)(INT)2(H2O)2 (ClO4)] (3), all containing natural amino acid l-HTrp (l-typtophan), were hydrothermally synthesized and structurally characterized. The compounds 1 and 2 crystallize in the orthorhombic space group C2221, with a = 10.731(2) Å, b = 19.709(4) Å, c = 27.365(6) Å and Z = 4 for 1 and a = 10.710(10) Å, b = 20.088(18) Å, c = 27.63(3) Å and Z = 8 for 2, respectively. The compound 3 has the monoclinic space group P21, with a = 8.1934(14) Å, b = 13.209(2) Å, c = 12.464(2) Å, β = 104.107(3)° and Z = 2. Both 1 and 2 consist of 1D helical chains. Compound 3 is composed of 2D networks, which further assemble into a 3D supramolecular structure via weak interlayer interactions. The optically pure amino acid l-HTrp plays an important role leading to homochiral structures reported here.

Original languageEnglish
Pages (from-to)1669-1677
Number of pages9
JournalInorganica Chimica Acta
Volume360
Issue number5
DOIs
Publication statusPublished - Apr 1 2007

Keywords

  • 2D networks
  • Chiral revulsive
  • Helical chain
  • Homochiral building unit
  • Natural l-typtophan coordination networks

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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  • Cite this

    Xie, Y., Yan, Y., Wu, H. H., Yong, G. P., Cui, Y., Wang, Z. Y., Pan, L., Li, J., Fan, R., Li, R. P., Tian, Y. C., Pan, G. Q., Sheng, L. S., & Li, X. (2007). Homochiral metal-organic coordination networks from l-typtophan. Inorganica Chimica Acta, 360(5), 1669-1677. https://doi.org/10.1016/j.ica.2006.09.032