Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C-N bond

M. Gandelman, David Milstein

Research output: Contribution to journalArticle

55 Citations (Scopus)


Reaction of [RhCl(COE)2]2 with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butyl-phosphinomethyl)-2,4,6-trimethylbenze ne (2) in dioxane under mild H2 pressure results in selective catalytic activation of an unstrained C-N single bond.

Original languageEnglish
Pages (from-to)1603-1604
Number of pages2
JournalChemical Communications
Issue number17
Publication statusPublished - Sep 7 2000


ASJC Scopus subject areas

  • Chemistry(all)

Cite this