Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C-N bond

M. Gandelman, David Milstein

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55 Citations (Scopus)

Abstract

Reaction of [RhCl(COE)2]2 with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butyl-phosphinomethyl)-2,4,6-trimethylbenze ne (2) in dioxane under mild H2 pressure results in selective catalytic activation of an unstrained C-N single bond.

Original languageEnglish
Pages (from-to)1603-1604
Number of pages2
JournalChemical Communications
Issue number17
Publication statusPublished - Sep 7 2000

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ASJC Scopus subject areas

  • Chemistry(all)

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