Hot Carrier and Surface Recombination Dynamics in Layered InSe Crystals

Chengmei Zhong, Vinod K. Sangwan, Joohoon Kang, Jan Luxa, Zdeněk Sofer, Mark C Hersam, Emily A Weiss

Research output: Contribution to journalArticle

Abstract

Layered indium selenide (InSe) is a van der Waals solid that has emerged as a promising material for high-performance ultrathin solar cells. The optoelectronic parameters that are critical to photoconversion efficiencies, such as hot carrier lifetime and surface recombination velocity, are however largely unexplored in InSe. Here, these key photophysical properties of layered InSe are measured with femtosecond transient reflection spectroscopy. The hot carrier cooling process is found to occur through phonon scattering. The surface recombination velocity and ambipolar diffusion coefficient are extracted from fits to the pump energy-dependent transient reflection kinetics using a free carrier diffusion model. The extracted surface recombination velocity is approximately an order of magnitude larger than that for methylammonium lead-iodide perovskites, suggesting that surface recombination is a principal source of photocarrier loss in InSe. The extracted ambipolar diffusion coefficient is consistent with previously reported values of InSe carrier mobility.

Original languageEnglish
Pages (from-to)493-499
Number of pages7
JournalJournal of Physical Chemistry Letters
DOIs
Publication statusAccepted/In press - Jan 1 2019

Fingerprint

indium selenides
Indium
Hot carriers
Crystals
ambipolar diffusion
crystals
diffusion coefficient
Phonon scattering
Carrier lifetime
Carrier mobility
Iodides
perovskites
carrier lifetime
carrier mobility
Optoelectronic devices
iodides
Solar cells
Lead
solar cells
Pumps

ASJC Scopus subject areas

  • Materials Science(all)
  • Physical and Theoretical Chemistry

Cite this

Hot Carrier and Surface Recombination Dynamics in Layered InSe Crystals. / Zhong, Chengmei; Sangwan, Vinod K.; Kang, Joohoon; Luxa, Jan; Sofer, Zdeněk; Hersam, Mark C; Weiss, Emily A.

In: Journal of Physical Chemistry Letters, 01.01.2019, p. 493-499.

Research output: Contribution to journalArticle

Zhong, Chengmei ; Sangwan, Vinod K. ; Kang, Joohoon ; Luxa, Jan ; Sofer, Zdeněk ; Hersam, Mark C ; Weiss, Emily A. / Hot Carrier and Surface Recombination Dynamics in Layered InSe Crystals. In: Journal of Physical Chemistry Letters. 2019 ; pp. 493-499.
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