Hybrid organic nanocrystal/carbon nanotube film electrodes for air- and photo-stable perovskite photovoltaics

Raja Bhaskar Kanth Siram, Mark V. Khenkin, Angelica Niazov-Elkan, K. M. Anoop, Haim Weissman, Eugene A. Katz, Iris Visoly-Fisher, Boris Rybtchinski

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Abstract

We report on utilizing free-standing hybrid perylenediimide/carbon nanotube (PDI/CNT) films fabricated in air as back contacts for fully inorganic perovskite solar cells (glass/FTO/dense TiO 2 /mesoporous TiO 2 /CsPbBr 3 /back electrode). The back contact electrode connection is performed by film transfer rather than by vacuum deposition or by wet processing, allowing the formation of highly homogeneous contacts under ambient conditions. The use of this novel electrode in solar cells based on CsPbBr 3 resulted in efficiency of 5.8% without a hole transporting layer; it is significantly improved in comparison to the reference cells with standard gold electrodes. Overall device fabrication can be performed on air, using inexpensive processing methods. The hybrid film electrodes dramatically improve the cell photo-stability under ambient conditions and under real-life operating conditions outdoors. The champion unencapsulated device demonstrated less than 30% efficiency loss over 6 weeks of outdoor aging in Negev desert conditions. The CNT/PDI electrodes offer the combination of fabrication simplicity, unique contacting approach, high efficiency and good operational stability for perovskite photovoltaics.

Original languageEnglish
Pages (from-to)3733-3740
Number of pages8
JournalNanoscale
Volume11
Issue number8
DOIs
Publication statusPublished - Feb 28 2019

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ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Siram, R. B. K., Khenkin, M. V., Niazov-Elkan, A., Anoop, K. M., Weissman, H., Katz, E. A., Visoly-Fisher, I., & Rybtchinski, B. (2019). Hybrid organic nanocrystal/carbon nanotube film electrodes for air- and photo-stable perovskite photovoltaics. Nanoscale, 11(8), 3733-3740. https://doi.org/10.1039/c8nr09353a