Hydride Transfer by Hydrido Transition‐Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex

Jeong‐Sup ‐S Song; David J. Szalda; R. Morris Bullock; Christophe J.C. Lawrie; Mikhail A. Rodkin; Jack R. Norton

doi:10.1002/anie.199212331

Hydride Transfer by Hydrido Transition‐Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex

Jeong‐Sup ‐S Song, David J. Szalda, R. Morris Bullock, Christophe J.C. Lawrie, Mikhail A. Rodkin, Jack R. Norton

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

83 Citations (Scopus)

Abstract

The rate‐determining step in the hydrogenation of aldehydes or ketones by hydrido complexes and acids appears to be the hydride transfer from the complex to the protonated carbonyl compound. The resulting alcohol is initially bound as ligand, as confirmed by an X‐ray crystal structure analysis of the alcohol complex 1. (Figure Presented.)

Original language	English
Pages (from-to)	1233-1235
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	31
Issue number	9
DOIs	https://doi.org/10.1002/anie.199212331
Publication status	Published - Sep 1992

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ASJC Scopus subject areas

Catalysis
Chemistry(all)

Cite this

Song, JS. S., Szalda, D. J., Bullock, R. M., Lawrie, C. J. C., Rodkin, M. A., & Norton, J. R. (1992). Hydride Transfer by Hydrido Transition‐Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex. Angewandte Chemie International Edition in English, 31(9), 1233-1235. https://doi.org/10.1002/anie.199212331

Hydride Transfer by Hydrido Transition‐Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex. / Song, Jeong‐Sup ‐S; Szalda, David J.; Bullock, R. Morris; Lawrie, Christophe J.C.; Rodkin, Mikhail A.; Norton, Jack R.

In: Angewandte Chemie International Edition in English, Vol. 31, No. 9, 09.1992, p. 1233-1235.

Research output: Contribution to journal › Article

Song, Jeong‐Sup ‐S ; Szalda, David J. ; Bullock, R. Morris ; Lawrie, Christophe J.C. ; Rodkin, Mikhail A. ; Norton, Jack R. / Hydride Transfer by Hydrido Transition‐Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex. In: Angewandte Chemie International Edition in English. 1992 ; Vol. 31, No. 9. pp. 1233-1235.

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10.1002/anie.199212331