Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst

Hagit Ben-Daat, Christopher L. Rock, Marco Flores, Thomas L. Groy, Amanda C. Bowman, Ryan Trovitch

Research output: Contribution to journal › Article

34 Citations (Scopus)

Abstract

Addition of NaEt3BH to (Ph2PPrDI)CoCl2 affords the corresponding monohydride, (Ph2PPrDI)CoH. X-ray diffraction and DFT calculations indicate that this compound possesses a radical monoanion α-DI chelate and a Co(ii) centre. Notably, (Ph2PPrDI)CoH catalyzes the hydroboration of alkynes and dihydroboration of nitriles under mild conditions.

Original languageEnglish
Pages (from-to)7333-7336
Number of pages4
JournalChemical Communications
Volume53
Issue number53
DOIs
Publication statusPublished - 2017

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Nitriles
Alkynes
Cobalt
Discrete Fourier transforms
Hydrides
X ray diffraction
Catalysts

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst. / Ben-Daat, Hagit; Rock, Christopher L.; Flores, Marco; Groy, Thomas L.; Bowman, Amanda C.; Trovitch, Ryan.

In: Chemical Communications, Vol. 53, No. 53, 2017, p. 7333-7336.

Research output: Contribution to journal › Article

Ben-Daat, H, Rock, CL, Flores, M, Groy, TL, Bowman, AC & Trovitch, R 2017, 'Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst', Chemical Communications, vol. 53, no. 53, pp. 7333-7336. https://doi.org/10.1039/c7cc02281f
Ben-Daat H, Rock CL, Flores M, Groy TL, Bowman AC, Trovitch R. Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst. Chemical Communications. 2017;53(53):7333-7336. https://doi.org/10.1039/c7cc02281f
Ben-Daat, Hagit ; Rock, Christopher L. ; Flores, Marco ; Groy, Thomas L. ; Bowman, Amanda C. ; Trovitch, Ryan. / Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst. In: Chemical Communications. 2017 ; Vol. 53, No. 53. pp. 7333-7336.
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