Hydrocarbon oxidation reactions on oxide surfaces

Kenneth R Poeppelmeier, Jason D. Pless, Natasha Erdman, Donggeun Ko, Laurence D. Marks, Peter C Stair

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Heterogeneous catalytic oxidations of hydrocarbons that employ metal oxide catalysts, which avoid the production of CO 2, will be increasingly importance in the field of industrial chemistry. Metal oxides convert short chain alkanes, e.g., butane, to alkenes and water by oxidative dehydrogenation. Thin films of Mg 3(VO 4) 2 is an excellent model catalyst. A study on the surface chemistry and the reversible reduction and oxidation of the underlying lattice is carried out. To grow high quality single crystals, the traveling solvent zone method is used. An atmosphere of flowing oxygen is required to stabilize V 5+ and grow crystals with few(er) defects. The growth of Mg 3(VO 4) single crystals are presented. This is an abstract of a paper presented at the 222nd ACS National Meting (Chicago, IL 8/26-30/2001).

Original languageEnglish
Title of host publicationACS Division of Environmental Chemistry, Preprints
Pages372-373
Number of pages2
Volume41
Edition2
Publication statusPublished - 2001
Event222nd ACS National Meeting - Chicago, IL, United States
Duration: Aug 26 2001Aug 30 2001

Other

Other222nd ACS National Meeting
CountryUnited States
CityChicago, IL
Period8/26/018/30/01

Fingerprint

Hydrocarbons
Oxides
Metals
Single crystals
Oxidation
Catalysts
Alkanes
Catalytic oxidation
Butane
Alkenes
Dehydrogenation
Carbon Monoxide
Surface chemistry
Interleukin-8
Paraffins
Olefins
Oxygen
Thin films
Defects
Crystals

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Energy(all)

Cite this

Poeppelmeier, K. R., Pless, J. D., Erdman, N., Ko, D., Marks, L. D., & Stair, P. C. (2001). Hydrocarbon oxidation reactions on oxide surfaces. In ACS Division of Environmental Chemistry, Preprints (2 ed., Vol. 41, pp. 372-373)

Hydrocarbon oxidation reactions on oxide surfaces. / Poeppelmeier, Kenneth R; Pless, Jason D.; Erdman, Natasha; Ko, Donggeun; Marks, Laurence D.; Stair, Peter C.

ACS Division of Environmental Chemistry, Preprints. Vol. 41 2. ed. 2001. p. 372-373.

Research output: Chapter in Book/Report/Conference proceedingChapter

Poeppelmeier, KR, Pless, JD, Erdman, N, Ko, D, Marks, LD & Stair, PC 2001, Hydrocarbon oxidation reactions on oxide surfaces. in ACS Division of Environmental Chemistry, Preprints. 2 edn, vol. 41, pp. 372-373, 222nd ACS National Meeting, Chicago, IL, United States, 8/26/01.
Poeppelmeier KR, Pless JD, Erdman N, Ko D, Marks LD, Stair PC. Hydrocarbon oxidation reactions on oxide surfaces. In ACS Division of Environmental Chemistry, Preprints. 2 ed. Vol. 41. 2001. p. 372-373
Poeppelmeier, Kenneth R ; Pless, Jason D. ; Erdman, Natasha ; Ko, Donggeun ; Marks, Laurence D. ; Stair, Peter C. / Hydrocarbon oxidation reactions on oxide surfaces. ACS Division of Environmental Chemistry, Preprints. Vol. 41 2. ed. 2001. pp. 372-373
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