Hydrogen evolution from organic "hydrides"

Daniel E. Schwarz, Thomas M. Cameron, Brian Scott, P. Jeffrey Hay, William Tumas, David L. Thorn

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Chemical hydrogen storage allows for a great flexibility and potential for meeting and possibly exceeding the DOE requirements for deliverable weight percent of H2. A series of organic compounds capable of evolving hydrogen at room temperature was studied. Dihydrobenzimidazoles (benzimidazolines) are well known as being easily oxidized and they are able to evolve hydrogen, in the presence of protons, and can be described as organic hydrides. Three derivatives of benzimidazolines were presented, which are capable of evolving hydrogen at room temperature in the presence of acid and catalysts such as finely divided palladium or RhCl(PPh3)3. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

Original languageEnglish
Title of host publicationACS National Meeting Book of Abstracts
Volume230
Publication statusPublished - 2005
Event230th ACS National Meeting - Washington, DC, United States
Duration: Aug 28 2005Sep 1 2005

Other

Other230th ACS National Meeting
CountryUnited States
CityWashington, DC
Period8/28/059/1/05

Fingerprint

Hydrides
Hydrogen
Hydrogen storage
Palladium
Organic compounds
Protons
Derivatives
Temperature
Catalysts
Acids
chlorotris(triphenylphosphine)rhodium

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Schwarz, D. E., Cameron, T. M., Scott, B., Hay, P. J., Tumas, W., & Thorn, D. L. (2005). Hydrogen evolution from organic "hydrides". In ACS National Meeting Book of Abstracts (Vol. 230)

Hydrogen evolution from organic "hydrides". / Schwarz, Daniel E.; Cameron, Thomas M.; Scott, Brian; Hay, P. Jeffrey; Tumas, William; Thorn, David L.

ACS National Meeting Book of Abstracts. Vol. 230 2005.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Schwarz, DE, Cameron, TM, Scott, B, Hay, PJ, Tumas, W & Thorn, DL 2005, Hydrogen evolution from organic "hydrides". in ACS National Meeting Book of Abstracts. vol. 230, 230th ACS National Meeting, Washington, DC, United States, 8/28/05.
Schwarz DE, Cameron TM, Scott B, Hay PJ, Tumas W, Thorn DL. Hydrogen evolution from organic "hydrides". In ACS National Meeting Book of Abstracts. Vol. 230. 2005
Schwarz, Daniel E. ; Cameron, Thomas M. ; Scott, Brian ; Hay, P. Jeffrey ; Tumas, William ; Thorn, David L. / Hydrogen evolution from organic "hydrides". ACS National Meeting Book of Abstracts. Vol. 230 2005.
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