Abstract
In 5.0 M H2O/acetonitrile, [(Ph2PPrPDI)MoO][PF6]2 produces H2 with 96% Faradaic efficiency at -2.5 V vs. Fc+/0 and a rate of 55 s-1. Reactivity studies and isolation of a Mo(ii) oxo intermediate, (Ph2PPrPDI)MoO, shed light on the H2 evolution mechanism.
Original language | English |
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Pages (from-to) | 11555-11558 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 52 |
Issue number | 77 |
DOIs | |
Publication status | Published - Jan 1 2016 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry