Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst

Raja Pal; Joseph A. Laureanti; Thomas L. Groy; Anne Katherine Jones; Ryan Trovitch

doi:10.1039/c6cc04946j

Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst

Raja Pal, Joseph A. Laureanti, Thomas L. Groy, Anne Katherine Jones, Ryan Trovitch

Arizona State University

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

In 5.0 M H₂O/acetonitrile, [(^Ph2PPrPDI)MoO][PF₆]₂ produces H₂ with 96% Faradaic efficiency at -2.5 V vs. Fc^+/0 and a rate of 55 s^-1. Reactivity studies and isolation of a Mo(ii) oxo intermediate, (^Ph2PPrPDI)MoO, shed light on the H₂ evolution mechanism.

Original language	English
Pages (from-to)	11555-11558
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	77
DOIs	https://doi.org/10.1039/c6cc04946j
Publication status	Published - 2016

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Pal, R., Laureanti, J. A., Groy, T. L., Jones, A. K., & Trovitch, R. (2016). Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst. Chemical Communications, 52(77), 11555-11558. https://doi.org/10.1039/c6cc04946j

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abstract = "In 5.0 M H2O/acetonitrile, [(Ph2PPrPDI)MoO][PF6]2 produces H2 with 96% Faradaic efficiency at -2.5 V vs. Fc+/0 and a rate of 55 s-1. Reactivity studies and isolation of a Mo(ii) oxo intermediate, (Ph2PPrPDI)MoO, shed light on the H2 evolution mechanism.",

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AU - Jones, Anne Katherine

AU - Trovitch, Ryan

PY - 2016

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AB - In 5.0 M H2O/acetonitrile, [(Ph2PPrPDI)MoO][PF6]2 produces H2 with 96% Faradaic efficiency at -2.5 V vs. Fc+/0 and a rate of 55 s-1. Reactivity studies and isolation of a Mo(ii) oxo intermediate, (Ph2PPrPDI)MoO, shed light on the H2 evolution mechanism.

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Access to Document

10.1039/c6cc04946j