Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst

Raja Pal; Joseph A. Laureanti; Thomas L. Groy; Anne K. Jones; Ryan J. Trovitch

doi:10.1039/c6cc04946j

Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst

Raja Pal, Joseph A. Laureanti, Thomas L. Groy, Anne K. Jones, Ryan J. Trovitch

Arizona State University

Research output: Contribution to journal › Article

8 Citations (Scopus)

Abstract

In 5.0 M H₂O/acetonitrile, [(^Ph2PPrPDI)MoO][PF₆]₂ produces H₂ with 96% Faradaic efficiency at -2.5 V vs. Fc^+/0 and a rate of 55 s^-1. Reactivity studies and isolation of a Mo(ii) oxo intermediate, (^Ph2PPrPDI)MoO, shed light on the H₂ evolution mechanism.

Original language	English
Pages (from-to)	11555-11558
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	77
DOIs	https://doi.org/10.1039/c6cc04946j
Publication status	Published - Jan 1 2016

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Pal, R., Laureanti, J. A., Groy, T. L., Jones, A. K., & Trovitch, R. J. (2016). Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst. Chemical Communications, 52(77), 11555-11558. https://doi.org/10.1039/c6cc04946j

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abstract = "In 5.0 M H2O/acetonitrile, [(Ph2PPrPDI)MoO][PF6]2 produces H2 with 96% Faradaic efficiency at -2.5 V vs. Fc+/0 and a rate of 55 s-1. Reactivity studies and isolation of a Mo(ii) oxo intermediate, (Ph2PPrPDI)MoO, shed light on the H2 evolution mechanism.",

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AU - Trovitch, Ryan J.

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