Hydrogenation of carbon dioxide to formate using ruthenium bis(diphosphino) complexes: Investigation of ligands containing proton relays

Brandon R. Galan, John C. Linehan, Aaron M. Appel, Mary C. Rakowski-DuBois, Daniel L. Dubois

Research output: Contribution to journalConference article

Abstract

Electrochemical and thermal catalysts for the conversion of CO 2 to CO, formate or formic acid are being developed with the goal of more efficient utilization of CO 2 to produce useful fuels. Ongoing research in our group is focused on understanding secondary coordination sphere effects in catalysis. Incorporation of proton relays (nitrogen based functionality) into the backbones of phopshine ligands has been shown to assist catalysis by assisting multi-proton and multi-electron processes. Previous efforts in the utilization of proton relays for hydrogen activation are being applied to Ru complexes bearing PNP or P 2N 2 ligand motifs. The synthesis and catalytic activity of these new complexes will be presented with direct comparison of ligands with and without proton relays.

Original languageEnglish
JournalACS National Meeting Book of Abstracts
Publication statusPublished - Dec 1 2011
Event242nd ACS National Meeting and Exposition - Denver, CO, United States
Duration: Aug 28 2011Sep 1 2011

    Fingerprint

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this