Abstract
Single crystals of the noncentrosymmetric KNaNbOF5 polymorph were grown for piezoelectric and triboluminescent measurements. Piezoelectric measurements yielded a d33 value of ±6.3 pCN-1 and an effective electromechanical coupling coefficient of up to 0.1565 in the frequency range 1960-2080 kHz. Crystals of KNaNbOF5 were found to exhibit a strong triboluminscence effect visible to the naked eye as blue sparks when crystals are crushed. This triboluminescence effect is uncommon in that it is likely independent from both the piezoelectric effect and atmospheric electrical discharge. Instead, triboluminescence may originate from crystal defects or be related to an electroluminescence effect.
| Original language | English |
|---|---|
| Pages (from-to) | 78-82 |
| Number of pages | 5 |
| Journal | Journal of Solid State Chemistry |
| Volume | 236 |
| DOIs | |
| Publication status | Published - Apr 1 2016 |
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Keywords
- Crystal growth
- Oxide-fluoride
- Piezoelectricity
- Triboluminescence
ASJC Scopus subject areas
- Condensed Matter Physics
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Ceramics and Composites
- Electronic, Optical and Magnetic Materials
- Materials Chemistry
Cite this
Hydrothermal crystal growth, piezoelectricity, and triboluminescence of KNaNbOF5 . / Chang, Kelvin B.; Edwards, Bryce W.; Frazer, Laszlo; Lenferink, Erik J.; Stanev, Teodor K.; Stern, Nathaniel P.; Nino, Juan C.; Poeppelmeier, Kenneth R.
In: Journal of Solid State Chemistry, Vol. 236, 01.04.2016, p. 78-82.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Hydrothermal crystal growth, piezoelectricity, and triboluminescence of KNaNbOF5
AU - Chang, Kelvin B.
AU - Edwards, Bryce W.
AU - Frazer, Laszlo
AU - Lenferink, Erik J.
AU - Stanev, Teodor K.
AU - Stern, Nathaniel P.
AU - Nino, Juan C.
AU - Poeppelmeier, Kenneth R
PY - 2016/4/1
Y1 - 2016/4/1
N2 - Single crystals of the noncentrosymmetric KNaNbOF5 polymorph were grown for piezoelectric and triboluminescent measurements. Piezoelectric measurements yielded a d33 value of ±6.3 pCN-1 and an effective electromechanical coupling coefficient of up to 0.1565 in the frequency range 1960-2080 kHz. Crystals of KNaNbOF5 were found to exhibit a strong triboluminscence effect visible to the naked eye as blue sparks when crystals are crushed. This triboluminescence effect is uncommon in that it is likely independent from both the piezoelectric effect and atmospheric electrical discharge. Instead, triboluminescence may originate from crystal defects or be related to an electroluminescence effect.
AB - Single crystals of the noncentrosymmetric KNaNbOF5 polymorph were grown for piezoelectric and triboluminescent measurements. Piezoelectric measurements yielded a d33 value of ±6.3 pCN-1 and an effective electromechanical coupling coefficient of up to 0.1565 in the frequency range 1960-2080 kHz. Crystals of KNaNbOF5 were found to exhibit a strong triboluminscence effect visible to the naked eye as blue sparks when crystals are crushed. This triboluminescence effect is uncommon in that it is likely independent from both the piezoelectric effect and atmospheric electrical discharge. Instead, triboluminescence may originate from crystal defects or be related to an electroluminescence effect.
KW - Crystal growth
KW - Oxide-fluoride
KW - Piezoelectricity
KW - Triboluminescence
UR - http://www.scopus.com/inward/record.url?scp=84965126035&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84965126035&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2015.07.011
DO - 10.1016/j.jssc.2015.07.011
M3 - Article
AN - SCOPUS:84965126035
VL - 236
SP - 78
EP - 82
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
ER -