Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr2Sn(OH)8

Mingmei Wu; Xiuling Li; Guoping Shen; Jing Li; Ruren Xu; Davide M. Proserpio

doi:10.1006/jssc.2000.8621

Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr₂Sn(OH)₈

Mingmei Wu, Xiuling Li, Guoping Shen, Jing Li, Ruren Xu, Davide M. Proserpio

Rutgers University

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A new hydroxo stannate(IV), Sr₂Sn(OH)₈, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P2₁/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å³, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]₂[Sn(OH)(6/3)] consists of Sn(OH)₆ octahedra and Sr(OH)₈ triangulated dodecahedra. These Sr(OH)₈ and Sn(OH)₆ polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

Original language	English
Pages (from-to)	56-60
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	151
Issue number	1
DOIs	https://doi.org/10.1006/jssc.2000.8621
Publication status	Published - 2000

Keywords

Extended framework
Hydrothermal synthesis
Structure
Tin(IV)

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Chemistry

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10.1006/jssc.2000.8621

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title = "Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr2Sn(OH)8",

abstract = "A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) {\AA}, b = 11.058(2) {\AA}, c = 6.129(2) {\AA}, β = 112.98(2)°, V = 374.8(2) {\AA}3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.",

keywords = "Extended framework, Hydrothermal synthesis, Structure, Tin(IV)",

author = "Mingmei Wu and Xiuling Li and Guoping Shen and Jing Li and Ruren Xu and Proserpio, {Davide M.}",

year = "2000",

doi = "10.1006/jssc.2000.8621",

language = "English",

volume = "151",

pages = "56--60",

journal = "Journal of Solid State Chemistry",

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T1 - Hydrothermal synthesis and structural characterization of a novel hydroxo stannate

T2 - Sr2Sn(OH)8

AU - Wu, Mingmei

AU - Li, Xiuling

AU - Shen, Guoping

AU - Li, Jing

AU - Xu, Ruren

AU - Proserpio, Davide M.

PY - 2000

Y1 - 2000

N2 - A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

AB - A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

KW - Extended framework

KW - Hydrothermal synthesis

KW - Structure

KW - Tin(IV)

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