Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr2Sn(OH)8

Mingmei Wu; Xiuling Li; Guoping Shen; Jing Li; Ruren Xu; Davide M. Proserpio

doi:10.1006/jssc.2000.8621

Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr₂Sn(OH)₈

Mingmei Wu, Xiuling Li, Guoping Shen, Jing Li, Ruren Xu, Davide M. Proserpio

Rutgers University

Research output: Contribution to journal › Article

17 Citations (Scopus)

Abstract

A new hydroxo stannate(IV), Sr₂Sn(OH)₈, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P2₁/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å³, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]₂[Sn(OH)(6/3)] consists of Sn(OH)₆ octahedra and Sr(OH)₈ triangulated dodecahedra. These Sr(OH)₈ and Sn(OH)₆ polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

Original language	English
Pages (from-to)	56-60
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	151
Issue number	1
DOIs	https://doi.org/10.1006/jssc.2000.8621
Publication status	Published - 2000

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Keywords

Extended framework
Hydrothermal synthesis
Structure
Tin(IV)

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Chemistry

Cite this

Wu, M., Li, X., Shen, G., Li, J., Xu, R., & Proserpio, D. M. (2000). Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr₂Sn(OH)₈. Journal of Solid State Chemistry, 151(1), 56-60. https://doi.org/10.1006/jssc.2000.8621

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title = "Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr2Sn(OH)8",

abstract = "A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) {\AA}, b = 11.058(2) {\AA}, c = 6.129(2) {\AA}, β = 112.98(2)°, V = 374.8(2) {\AA}3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.",

keywords = "Extended framework, Hydrothermal synthesis, Structure, Tin(IV)",

author = "Mingmei Wu and Xiuling Li and Guoping Shen and Jing Li and Ruren Xu and Proserpio, {Davide M.}",

year = "2000",

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AU - Shen, Guoping

AU - Li, Jing

AU - Xu, Ruren

AU - Proserpio, Davide M.

PY - 2000

Y1 - 2000

N2 - A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

AB - A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

KW - Extended framework

KW - Hydrothermal synthesis

KW - Structure

KW - Tin(IV)

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10.1006/jssc.2000.8621