Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr2Sn(OH)8

Mingmei Wu, Xiuling Li, Guoping Shen, Jing Li, Ruren Xu, Davide M. Proserpio

Research output: Contribution to journal › Article

17 Citations (Scopus)

Abstract

A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

Original languageEnglish
Pages (from-to)56-60
Number of pages5
JournalJournal of Solid State Chemistry
Volume151
Issue number1
DOIs
Publication statusPublished - 2000

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stannates
Hydrothermal synthesis
Hydrogen
Single crystals
X ray diffraction
synthesis
polyhedrons
single crystals
hydrogen
diffraction
x rays

Keywords

  • Extended framework
  • Hydrothermal synthesis
  • Structure
  • Tin(IV)

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Hydrothermal synthesis and structural characterization of a novel hydroxo stannate : Sr2Sn(OH)8. / Wu, Mingmei; Li, Xiuling; Shen, Guoping; Li, Jing; Xu, Ruren; Proserpio, Davide M.

In: Journal of Solid State Chemistry, Vol. 151, No. 1, 2000, p. 56-60.

Research output: Contribution to journal › Article

Wu, M, Li, X, Shen, G, Li, J, Xu, R & Proserpio, DM 2000, 'Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr2Sn(OH)8', Journal of Solid State Chemistry, vol. 151, no. 1, pp. 56-60. https://doi.org/10.1006/jssc.2000.8621
Wu M, Li X, Shen G, Li J, Xu R, Proserpio DM. Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr2Sn(OH)8. Journal of Solid State Chemistry. 2000;151(1):56-60. https://doi.org/10.1006/jssc.2000.8621
Wu, Mingmei ; Li, Xiuling ; Shen, Guoping ; Li, Jing ; Xu, Ruren ; Proserpio, Davide M. / Hydrothermal synthesis and structural characterization of a novel hydroxo stannate : Sr2Sn(OH)8. In: Journal of Solid State Chemistry. 2000 ; Vol. 151, No. 1. pp. 56-60.
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abstract = "A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) {\AA}, b = 11.058(2) {\AA}, c = 6.129(2) {\AA}, β = 112.98(2)°, V = 374.8(2) {\AA}3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.",
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AU - Shen, Guoping

AU - Li, Jing

AU - Xu, Ruren

AU - Proserpio, Davide M.

PY - 2000

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N2 - A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

AB - A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

KW - Extended framework

KW - Hydrothermal synthesis

KW - Structure

KW - Tin(IV)

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