Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr2Sn(OH)8

Mingmei Wu; Xiuling Li; Guoping Shen; Jing Li; Ruren Xu; Davide M. Proserpio

doi:10.1006/jssc.2000.8621

Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr₂Sn(OH)₈

Mingmei Wu, Xiuling Li, Guoping Shen, Jing Li, Ruren Xu, Davide M. Proserpio

Rutgers University

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A new hydroxo stannate(IV), Sr₂Sn(OH)₈, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P2₁/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å³, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]₂[Sn(OH)(6/3)] consists of Sn(OH)₆ octahedra and Sr(OH)₈ triangulated dodecahedra. These Sr(OH)₈ and Sn(OH)₆ polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

Original language	English
Pages (from-to)	56-60
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	151
Issue number	1
DOIs	https://doi.org/10.1006/jssc.2000.8621
Publication status	Published - 2000

Keywords

Extended framework
Hydrothermal synthesis
Structure
Tin(IV)

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Hydrothermal synthesis and structural characterization of a novel hydroxo stannate: Sr2Sn(OH)8",

abstract = "A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) {\AA}, b = 11.058(2) {\AA}, c = 6.129(2) {\AA}, β = 112.98(2)°, V = 374.8(2) {\AA}3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.",

keywords = "Extended framework, Hydrothermal synthesis, Structure, Tin(IV)",

author = "Mingmei Wu and Xiuling Li and Guoping Shen and Jing Li and Ruren Xu and Proserpio, {Davide M.}",

note = "Funding Information: We gratefully acknowledge the {"}nancial support of the National Natural Science Foundation of China, Provincial Natural Science Foundation of China, and the Key Laboratory of IHS. The authors appreciate Dr. Su Chengyong for helpful discussions. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.",

year = "2000",

doi = "10.1006/jssc.2000.8621",

language = "English",

volume = "151",

pages = "56--60",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "1",

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TY - JOUR

T1 - Hydrothermal synthesis and structural characterization of a novel hydroxo stannate

T2 - Sr2Sn(OH)8

AU - Wu, Mingmei

AU - Li, Xiuling

AU - Shen, Guoping

AU - Li, Jing

AU - Xu, Ruren

AU - Proserpio, Davide M.

N1 - Funding Information: We gratefully acknowledge the "nancial support of the National Natural Science Foundation of China, Provincial Natural Science Foundation of China, and the Key Laboratory of IHS. The authors appreciate Dr. Su Chengyong for helpful discussions. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.

PY - 2000

Y1 - 2000

N2 - A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

AB - A new hydroxo stannate(IV), Sr2Sn(OH)8, has been synthesized by the hydrothermal method. Single-crystal X-ray diffraction shows that this compound crystallizes in the monoclinic space group P21/c with a = 6.006(1) Å, b = 11.058(2) Å, c = 6.129(2) Å, β = 112.98(2)°, V = 374.8(2) Å3, Z = 2, R = 0.022 (I > 2 σ(I)). The structure [Sr(OH)(6/3)(OH)(2/2)]2[Sn(OH)(6/3)] consists of Sn(OH)6 octahedra and Sr(OH)8 triangulated dodecahedra. These Sr(OH)8 and Sn(OH)6 polyhedra form a novel complex 3D packing arrangement that contains channels running along [001], filled with the in-pointing hydrogens of the hydroxo groups. (C) 2000 Academic Press.

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