Abstract
The hydrothermal reaction of PdCl2 with K2Se4 in the presence of different KOH and water in the 1:5:5:40 ratio produced K2[PdSe10] (I), the first metal polychalcogenide compound containing two interpenetrating three-dimensional frameworks. The black rectangular chunky crystals of I are insoluble in water and most organic solvents. They crystallize in the orthorhombic space group I212121 (no. 24) with a = 15.872 (9) Å, b = 15.922 (9) Å, c = 12.885 (8) Å, V = 3256 (6) Å3. I is composed of two independent interpenetrating 3D diamond-like frameworks of [Pd(Se4)2]2- and [Pd(Se6)2]2-. Each framework contains large tunnels running parallel to the a- and b-crystallographic axes. The coordination geometry around Pd is square-planar. The average Pd-Se and Se-Se distances are 2.462 (5) and 2.35 (2) Å, respectively. The closest distances between K+ ions and Se atoms are in the range of 3.27 (2) and 3.75 (2) Å.
| Original language | English |
|---|---|
| Pages (from-to) | 4878-4883 |
| Number of pages | 6 |
| Journal | Journal of the American Chemical Society |
| Volume | 114 |
| Issue number | 12 |
| Publication status | Published - 1992 |
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Hydrothermal synthesis of K2PdSe10. Coexistence of two large interpenetrating three-dimensional frameworks of [Pd(Se4)2]2- and [Pd(Se6)2]2-. / Kim, Kang Woo; Kanatzidis, Mercouri G.
In: Journal of the American Chemical Society, Vol. 114, No. 12, 1992, p. 4878-4883.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Hydrothermal synthesis of K2PdSe10. Coexistence of two large interpenetrating three-dimensional frameworks of [Pd(Se4)2]2- and [Pd(Se6)2]2-
AU - Kim, Kang Woo
AU - Kanatzidis, Mercouri G
PY - 1992
Y1 - 1992
N2 - The hydrothermal reaction of PdCl2 with K2Se4 in the presence of different KOH and water in the 1:5:5:40 ratio produced K2[PdSe10] (I), the first metal polychalcogenide compound containing two interpenetrating three-dimensional frameworks. The black rectangular chunky crystals of I are insoluble in water and most organic solvents. They crystallize in the orthorhombic space group I212121 (no. 24) with a = 15.872 (9) Å, b = 15.922 (9) Å, c = 12.885 (8) Å, V = 3256 (6) Å3. I is composed of two independent interpenetrating 3D diamond-like frameworks of [Pd(Se4)2]2- and [Pd(Se6)2]2-. Each framework contains large tunnels running parallel to the a- and b-crystallographic axes. The coordination geometry around Pd is square-planar. The average Pd-Se and Se-Se distances are 2.462 (5) and 2.35 (2) Å, respectively. The closest distances between K+ ions and Se atoms are in the range of 3.27 (2) and 3.75 (2) Å.
AB - The hydrothermal reaction of PdCl2 with K2Se4 in the presence of different KOH and water in the 1:5:5:40 ratio produced K2[PdSe10] (I), the first metal polychalcogenide compound containing two interpenetrating three-dimensional frameworks. The black rectangular chunky crystals of I are insoluble in water and most organic solvents. They crystallize in the orthorhombic space group I212121 (no. 24) with a = 15.872 (9) Å, b = 15.922 (9) Å, c = 12.885 (8) Å, V = 3256 (6) Å3. I is composed of two independent interpenetrating 3D diamond-like frameworks of [Pd(Se4)2]2- and [Pd(Se6)2]2-. Each framework contains large tunnels running parallel to the a- and b-crystallographic axes. The coordination geometry around Pd is square-planar. The average Pd-Se and Se-Se distances are 2.462 (5) and 2.35 (2) Å, respectively. The closest distances between K+ ions and Se atoms are in the range of 3.27 (2) and 3.75 (2) Å.
UR - http://www.scopus.com/inward/record.url?scp=2742572502&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=2742572502&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:2742572502
VL - 114
SP - 4878
EP - 4883
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 12
ER -