Abstract
Bio-inspired complexes with hydroxy-substituted pyridine-like N-heterocyclic ligands have been applied in homogeneous catalysis, especially in transformations related to hydrogen storage. The hydroxy functional group has a significant effect on catalyst activation by acting as an electron donor and/or pendent base. This article presents the design and synthesis of new complexes with pyridine-like N-heterocyclic ligands bearing versatile hydroxy functional groups. Their application for the activation of small molecules such as H 2, CO2, and alcohols and their potential contribution to the hydrogen economy are highlighted.
Original language | English |
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Pages (from-to) | 1860-1866 |
Number of pages | 7 |
Journal | New Journal of Chemistry |
Volume | 37 |
Issue number | 7 |
DOIs | |
Publication status | Published - Jul 2013 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Materials Chemistry