Abstract
Bio-inspired complexes with hydroxy-substituted pyridine-like N-heterocyclic ligands have been applied in homogeneous catalysis, especially in transformations related to hydrogen storage. The hydroxy functional group has a significant effect on catalyst activation by acting as an electron donor and/or pendent base. This article presents the design and synthesis of new complexes with pyridine-like N-heterocyclic ligands bearing versatile hydroxy functional groups. Their application for the activation of small molecules such as H 2, CO2, and alcohols and their potential contribution to the hydrogen economy are highlighted.
| Original language | English |
|---|---|
| Pages (from-to) | 1860-1866 |
| Number of pages | 7 |
| Journal | New Journal of Chemistry |
| Volume | 37 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Jul 2013 |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Materials Chemistry
Cite this
Hydroxy-substituted pyridine-like N-heterocycles : Versatile ligands in organometallic catalysis. / Wang, Wan Hui; Muckerman, James T.; Fujita, Etsuko; Himeda, Yuichiro.
In: New Journal of Chemistry, Vol. 37, No. 7, 07.2013, p. 1860-1866.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Hydroxy-substituted pyridine-like N-heterocycles
T2 - Versatile ligands in organometallic catalysis
AU - Wang, Wan Hui
AU - Muckerman, James T.
AU - Fujita, Etsuko
AU - Himeda, Yuichiro
PY - 2013/7
Y1 - 2013/7
N2 - Bio-inspired complexes with hydroxy-substituted pyridine-like N-heterocyclic ligands have been applied in homogeneous catalysis, especially in transformations related to hydrogen storage. The hydroxy functional group has a significant effect on catalyst activation by acting as an electron donor and/or pendent base. This article presents the design and synthesis of new complexes with pyridine-like N-heterocyclic ligands bearing versatile hydroxy functional groups. Their application for the activation of small molecules such as H 2, CO2, and alcohols and their potential contribution to the hydrogen economy are highlighted.
AB - Bio-inspired complexes with hydroxy-substituted pyridine-like N-heterocyclic ligands have been applied in homogeneous catalysis, especially in transformations related to hydrogen storage. The hydroxy functional group has a significant effect on catalyst activation by acting as an electron donor and/or pendent base. This article presents the design and synthesis of new complexes with pyridine-like N-heterocyclic ligands bearing versatile hydroxy functional groups. Their application for the activation of small molecules such as H 2, CO2, and alcohols and their potential contribution to the hydrogen economy are highlighted.
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UR - http://www.scopus.com/inward/citedby.url?scp=84884658059&partnerID=8YFLogxK
U2 - 10.1039/c3nj41146j
DO - 10.1039/c3nj41146j
M3 - Article
VL - 37
SP - 1860
EP - 1866
JO - New Journal of Chemistry
JF - New Journal of Chemistry
SN - 1144-0546
IS - 7
ER -