Imaging O(3P)+alkane reactions in crossed molecular beams: Vertical versus adiabatic H abstraction dynamics

Xianghong Liu, Richard L. Gross, Gregory E. Hall, James Muckerman, Arthur G. Suits

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

The imaging of O(3P)+alkane reactions in crossed molecular beams was studied by using velocity map imaging of the alkyl radical product. The differential cross sections and translational energy distributions for reaction of O(3P) with cyclohexane, n-butane and isobutane was obtained at collision energies ranging from 4.7 kcal/mol to 14.8 kcal/mol. The results showed low average translational energy release on the order of 40% of the available energy.

Original languageEnglish
Pages (from-to)7947-7959
Number of pages13
JournalJournal of Chemical Physics
Volume117
Issue number17
DOIs
Publication statusPublished - Nov 1 2002

Fingerprint

Alkanes
Molecular beams
alkanes
molecular beams
Butanes
butanes
Imaging techniques
cyclohexane
energy
energy distribution
collisions
cross sections
products
Cyclohexane
butane

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Imaging O(3P)+alkane reactions in crossed molecular beams : Vertical versus adiabatic H abstraction dynamics. / Liu, Xianghong; Gross, Richard L.; Hall, Gregory E.; Muckerman, James; Suits, Arthur G.

In: Journal of Chemical Physics, Vol. 117, No. 17, 01.11.2002, p. 7947-7959.

Research output: Contribution to journalArticle

Liu, Xianghong ; Gross, Richard L. ; Hall, Gregory E. ; Muckerman, James ; Suits, Arthur G. / Imaging O(3P)+alkane reactions in crossed molecular beams : Vertical versus adiabatic H abstraction dynamics. In: Journal of Chemical Physics. 2002 ; Vol. 117, No. 17. pp. 7947-7959.
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