Imaging O(3P)+alkane reactions in crossed molecular beams: Vertical versus adiabatic H abstraction dynamics

Xianghong Liu; Richard L. Gross; Gregory E. Hall; James T. Muckerman; Arthur G. Suits

doi:10.1063/1.1510444

Imaging O(³P)+alkane reactions in crossed molecular beams: Vertical versus adiabatic H abstraction dynamics

Xianghong Liu, Richard L. Gross, Gregory E. Hall, James T. Muckerman, Arthur G. Suits

Brookhaven National Laboratory

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The imaging of O(³P)+alkane reactions in crossed molecular beams was studied by using velocity map imaging of the alkyl radical product. The differential cross sections and translational energy distributions for reaction of O(³P) with cyclohexane, n-butane and isobutane was obtained at collision energies ranging from 4.7 kcal/mol to 14.8 kcal/mol. The results showed low average translational energy release on the order of 40% of the available energy.

Original language	English
Pages (from-to)	7947-7959
Number of pages	13
Journal	Journal of Chemical Physics
Volume	117
Issue number	17
DOIs	https://doi.org/10.1063/1.1510444
Publication status	Published - Nov 1 2002

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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AU - Muckerman, James T.

AU - Suits, Arthur G.

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