Imaging O(3P)+alkane reactions in crossed molecular beams: Vertical versus adiabatic H abstraction dynamics

Xianghong Liu; Richard L. Gross; Gregory E. Hall; James T. Muckerman; Arthur G. Suits

doi:10.1063/1.1510444

Imaging O(³P)+alkane reactions in crossed molecular beams: Vertical versus adiabatic H abstraction dynamics

Xianghong Liu, Richard L. Gross, Gregory E. Hall, James T. Muckerman, Arthur G. Suits

Brookhaven National Laboratory

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35 Citations (Scopus)

Abstract

The imaging of O(³P)+alkane reactions in crossed molecular beams was studied by using velocity map imaging of the alkyl radical product. The differential cross sections and translational energy distributions for reaction of O(³P) with cyclohexane, n-butane and isobutane was obtained at collision energies ranging from 4.7 kcal/mol to 14.8 kcal/mol. The results showed low average translational energy release on the order of 40% of the available energy.

Original language	English
Pages (from-to)	7947-7959
Number of pages	13
Journal	Journal of Chemical Physics
Volume	117
Issue number	17
DOIs	https://doi.org/10.1063/1.1510444
Publication status	Published - Nov 1 2002

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ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Cite this

Liu, X., Gross, R. L., Hall, G. E., Muckerman, J. T., & Suits, A. G. (2002). Imaging O(³P)+alkane reactions in crossed molecular beams: Vertical versus adiabatic H abstraction dynamics. Journal of Chemical Physics, 117(17), 7947-7959. https://doi.org/10.1063/1.1510444

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10.1063/1.1510444