Abstract
The imaging of O(3P)+alkane reactions in crossed molecular beams was studied by using velocity map imaging of the alkyl radical product. The differential cross sections and translational energy distributions for reaction of O(3P) with cyclohexane, n-butane and isobutane was obtained at collision energies ranging from 4.7 kcal/mol to 14.8 kcal/mol. The results showed low average translational energy release on the order of 40% of the available energy.
| Original language | English |
|---|---|
| Pages (from-to) | 7947-7959 |
| Number of pages | 13 |
| Journal | Journal of Chemical Physics |
| Volume | 117 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - Nov 1 2002 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Cite this
Imaging O(3P)+alkane reactions in crossed molecular beams : Vertical versus adiabatic H abstraction dynamics. / Liu, Xianghong; Gross, Richard L.; Hall, Gregory E.; Muckerman, James; Suits, Arthur G.
In: Journal of Chemical Physics, Vol. 117, No. 17, 01.11.2002, p. 7947-7959.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Imaging O(3P)+alkane reactions in crossed molecular beams
T2 - Vertical versus adiabatic H abstraction dynamics
AU - Liu, Xianghong
AU - Gross, Richard L.
AU - Hall, Gregory E.
AU - Muckerman, James
AU - Suits, Arthur G.
PY - 2002/11/1
Y1 - 2002/11/1
N2 - The imaging of O(3P)+alkane reactions in crossed molecular beams was studied by using velocity map imaging of the alkyl radical product. The differential cross sections and translational energy distributions for reaction of O(3P) with cyclohexane, n-butane and isobutane was obtained at collision energies ranging from 4.7 kcal/mol to 14.8 kcal/mol. The results showed low average translational energy release on the order of 40% of the available energy.
AB - The imaging of O(3P)+alkane reactions in crossed molecular beams was studied by using velocity map imaging of the alkyl radical product. The differential cross sections and translational energy distributions for reaction of O(3P) with cyclohexane, n-butane and isobutane was obtained at collision energies ranging from 4.7 kcal/mol to 14.8 kcal/mol. The results showed low average translational energy release on the order of 40% of the available energy.
UR - http://www.scopus.com/inward/record.url?scp=0036850676&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0036850676&partnerID=8YFLogxK
U2 - 10.1063/1.1510444
DO - 10.1063/1.1510444
M3 - Article
AN - SCOPUS:0036850676
VL - 117
SP - 7947
EP - 7959
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 17
ER -