Imine-linked microporous polymer organic frameworks

Prativa Pandey, Alexandros P. Katsoulidis, Ibrahim Eryazici, Yuyang Wu, Mercouri G Kanatzidis, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

159 Citations (Scopus)

Abstract

Imine-linked microporous polymer organic frameworks (POFs) were synthesized via Schiff base condensation between 1,3,5-triformylbenzene and several readily available diamine monomers. Our facile, one-pot approach results in quantitative yields of POFs with the flexibility to incorporate several functional groups in their pores for tuning the interaction of their surface with different guest molecules. Synthesized POFs exhibit high specific surface areas (up to 1500 m2 g-1) as well as high isosteric heats of H2 adsorption (up to 8.2 kJ mol-1).

Original languageEnglish
Pages (from-to)4974-4979
Number of pages6
JournalChemistry of Materials
Volume22
Issue number17
DOIs
Publication statusPublished - Sep 14 2010

Fingerprint

Imines
Organic polymers
Diamines
Schiff Bases
Specific surface area
Functional groups
Condensation
Tuning
Monomers
Adsorption
Molecules

ASJC Scopus subject areas

  • Materials Chemistry
  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Pandey, P., Katsoulidis, A. P., Eryazici, I., Wu, Y., Kanatzidis, M. G., & Nguyen, S. T. (2010). Imine-linked microporous polymer organic frameworks. Chemistry of Materials, 22(17), 4974-4979. https://doi.org/10.1021/cm101157w

Imine-linked microporous polymer organic frameworks. / Pandey, Prativa; Katsoulidis, Alexandros P.; Eryazici, Ibrahim; Wu, Yuyang; Kanatzidis, Mercouri G; Nguyen, Sonbinh T.

In: Chemistry of Materials, Vol. 22, No. 17, 14.09.2010, p. 4974-4979.

Research output: Contribution to journalArticle

Pandey, P, Katsoulidis, AP, Eryazici, I, Wu, Y, Kanatzidis, MG & Nguyen, ST 2010, 'Imine-linked microporous polymer organic frameworks', Chemistry of Materials, vol. 22, no. 17, pp. 4974-4979. https://doi.org/10.1021/cm101157w
Pandey P, Katsoulidis AP, Eryazici I, Wu Y, Kanatzidis MG, Nguyen ST. Imine-linked microporous polymer organic frameworks. Chemistry of Materials. 2010 Sep 14;22(17):4974-4979. https://doi.org/10.1021/cm101157w
Pandey, Prativa ; Katsoulidis, Alexandros P. ; Eryazici, Ibrahim ; Wu, Yuyang ; Kanatzidis, Mercouri G ; Nguyen, Sonbinh T. / Imine-linked microporous polymer organic frameworks. In: Chemistry of Materials. 2010 ; Vol. 22, No. 17. pp. 4974-4979.
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