Improved Environmental Stability and Solar Cell Efficiency of (MA,FA)PbI3 Perovskite Using a Wide-Band-Gap 1D Thiazolium Lead Iodide Capping Layer Strategy

Lili Gao, Ioannis Spanopoulos, Weijun Ke, Sheng Huang, Ido Hadar, Lin Chen, Xiaolei Li, Guanjun Yang, Mercouri G. Kanatzidis

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

There is strong interest in improving the environmental stability of hybrid perovskite solar cells while maintaining high efficiency. Here, we solve this problem by using epilayers of a wide-band-gap 1D lead iodide perovskitoid structure, based on a short organic cation, namely, thiazole ammonium (TA) in the form of lead iodide (TAPbI3). The 1D capping layer serves to passivate three-dimensional (3D) perovskite films, which promotes charge transport, improves carrier lifetime, and prevents iodide ion migration of the 3D (MA,FA)PbI3 film (MA = methylammonium, FA = formamidinium). Furthermore, the corresponding device achieved considerable efficiency and better environmental stability than the -based analogue, delivering a champion PCE value of 18.97% while retaining 92% of this efficiency under ambient conditions in air for 2 months. These findings suggest that utilization of a 1D perovskitoid is an effective strategy to improve the environmental stability of 3D-based perovskite solar cell devices maintaining at the same time their high efficiency.

Original languageEnglish
Pages (from-to)1763-1769
Number of pages7
JournalACS Energy Letters
Volume4
Issue number7
DOIs
Publication statusPublished - Jun 26 2019

Fingerprint

Iodides
Perovskite
Solar cells
Energy gap
Lead
Thiazoles
Carrier lifetime
Epilayers
Ammonium Compounds
Cations
Charge transfer
Positive ions
Ions
perovskite
Air
Perovskite solar cells

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

Cite this

Improved Environmental Stability and Solar Cell Efficiency of (MA,FA)PbI3 Perovskite Using a Wide-Band-Gap 1D Thiazolium Lead Iodide Capping Layer Strategy. / Gao, Lili; Spanopoulos, Ioannis; Ke, Weijun; Huang, Sheng; Hadar, Ido; Chen, Lin; Li, Xiaolei; Yang, Guanjun; Kanatzidis, Mercouri G.

In: ACS Energy Letters, Vol. 4, No. 7, 26.06.2019, p. 1763-1769.

Research output: Contribution to journalArticle

Gao, Lili ; Spanopoulos, Ioannis ; Ke, Weijun ; Huang, Sheng ; Hadar, Ido ; Chen, Lin ; Li, Xiaolei ; Yang, Guanjun ; Kanatzidis, Mercouri G. / Improved Environmental Stability and Solar Cell Efficiency of (MA,FA)PbI3 Perovskite Using a Wide-Band-Gap 1D Thiazolium Lead Iodide Capping Layer Strategy. In: ACS Energy Letters. 2019 ; Vol. 4, No. 7. pp. 1763-1769.
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AU - Hadar, Ido

AU - Chen, Lin

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AU - Yang, Guanjun

AU - Kanatzidis, Mercouri G.

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