Abstract
A new microporous europium-containing metal-organic framework [Eu 2(μ2-pzdc)(μ4-pzdc)(μ2-ox) (H2O)4]·8H2O (1) (H2pzdc = 2,5-pyrazinedicarboxylic acid, H2ox = oxalic acid) has been hydrothermally synthesized via an unprecedented in situ formation of 2,5-pyrazinedicarboxylate (pzdc) and oxalate (ox) ligands. Structure 1 was characterized by both single-crystal and powder X-ray diffraction analysis. It can be described as a 4-connected binodal Moganite network with the Schläfli symbol of (4·64·8)2(4 2·62·82), which exhibits a reversible and highly selective sensing function with respect to acetone.
| Original language | English |
|---|---|
| Pages (from-to) | 4372-4377 |
| Number of pages | 6 |
| Journal | CrystEngComm |
| Volume | 12 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - Dec 2010 |
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ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium-organic framework capable of selective sensing of small molecules. / Ma, Deyun; Wang, Weixia; Li, Yingwei; Li, Jing; Daiguebonne, Carole; Calvez, Guillaume; Guillou, Olivier.
In: CrystEngComm, Vol. 12, No. 12, 12.2010, p. 4372-4377.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium-organic framework capable of selective sensing of small molecules
AU - Ma, Deyun
AU - Wang, Weixia
AU - Li, Yingwei
AU - Li, Jing
AU - Daiguebonne, Carole
AU - Calvez, Guillaume
AU - Guillou, Olivier
PY - 2010/12
Y1 - 2010/12
N2 - A new microporous europium-containing metal-organic framework [Eu 2(μ2-pzdc)(μ4-pzdc)(μ2-ox) (H2O)4]·8H2O (1) (H2pzdc = 2,5-pyrazinedicarboxylic acid, H2ox = oxalic acid) has been hydrothermally synthesized via an unprecedented in situ formation of 2,5-pyrazinedicarboxylate (pzdc) and oxalate (ox) ligands. Structure 1 was characterized by both single-crystal and powder X-ray diffraction analysis. It can be described as a 4-connected binodal Moganite network with the Schläfli symbol of (4·64·8)2(4 2·62·82), which exhibits a reversible and highly selective sensing function with respect to acetone.
AB - A new microporous europium-containing metal-organic framework [Eu 2(μ2-pzdc)(μ4-pzdc)(μ2-ox) (H2O)4]·8H2O (1) (H2pzdc = 2,5-pyrazinedicarboxylic acid, H2ox = oxalic acid) has been hydrothermally synthesized via an unprecedented in situ formation of 2,5-pyrazinedicarboxylate (pzdc) and oxalate (ox) ligands. Structure 1 was characterized by both single-crystal and powder X-ray diffraction analysis. It can be described as a 4-connected binodal Moganite network with the Schläfli symbol of (4·64·8)2(4 2·62·82), which exhibits a reversible and highly selective sensing function with respect to acetone.
UR - http://www.scopus.com/inward/record.url?scp=78349241100&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=78349241100&partnerID=8YFLogxK
U2 - 10.1039/c0ce00135j
DO - 10.1039/c0ce00135j
M3 - Article
VL - 12
SP - 4372
EP - 4377
JO - CrystEngComm
JF - CrystEngComm
SN - 1466-8033
IS - 12
ER -