In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium-organic framework capable of selective sensing of small molecules

Deyun Ma, Weixia Wang, Yingwei Li, Jing Li, Carole Daiguebonne, Guillaume Calvez, Olivier Guillou

Research output: Contribution to journalArticle

126 Citations (Scopus)

Abstract

A new microporous europium-containing metal-organic framework [Eu 22-pzdc)(μ4-pzdc)(μ2-ox) (H2O)4]·8H2O (1) (H2pzdc = 2,5-pyrazinedicarboxylic acid, H2ox = oxalic acid) has been hydrothermally synthesized via an unprecedented in situ formation of 2,5-pyrazinedicarboxylate (pzdc) and oxalate (ox) ligands. Structure 1 was characterized by both single-crystal and powder X-ray diffraction analysis. It can be described as a 4-connected binodal Moganite network with the Schläfli symbol of (4·64·8)2(4 2·62·82), which exhibits a reversible and highly selective sensing function with respect to acetone.

Original languageEnglish
Pages (from-to)4372-4377
Number of pages6
JournalCrystEngComm
Volume12
Issue number12
DOIs
Publication statusPublished - Dec 2010

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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