In situ dimanganese catalyst for fast screening of molecular recognition catalysts for regioselective oxygenation of an sp3 C-H bond

Siddhartha Das; Gary W. Brudvig; Robert H. Crabtree

doi:10.1016/j.ica.2008.06.009

In situ dimanganese catalyst for fast screening of molecular recognition catalysts for regioselective oxygenation of an sp³ C-H bond

Siddhartha Das, Gary W. Brudvig, Robert H. Crabtree

Yale University

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O₂-assay study and its regioselective C-H activation activity by product analysis in catalytic runs.

Original language	English
Pages (from-to)	1229-1233
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	362
Issue number	4
DOIs	https://doi.org/10.1016/j.ica.2008.06.009
Publication status	Published - Mar 2 2009

Keywords

Hydrogen bond

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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abstract = "We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O2-assay study and its regioselective C-H activation activity by product analysis in catalytic runs.",

keywords = "Hydrogen bond",

author = "Siddhartha Das and Brudvig, {Gary W.} and Crabtree, {Robert H.}",

note = "Funding Information: This work was supported by National Science Foundation (CHE-0614403) and NIH (GM32715)",

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AU - Das, Siddhartha

AU - Brudvig, Gary W.

AU - Crabtree, Robert H.

N1 - Funding Information: This work was supported by National Science Foundation (CHE-0614403) and NIH (GM32715)

PY - 2009/3/2

Y1 - 2009/3/2

N2 - We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O2-assay study and its regioselective C-H activation activity by product analysis in catalytic runs.

AB - We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O2-assay study and its regioselective C-H activation activity by product analysis in catalytic runs.

KW - Hydrogen bond

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