In situ dimanganese catalyst for fast screening of molecular recognition catalysts for regioselective oxygenation of an sp3 C-H bond

Siddhartha Das, Gary W Brudvig, Robert H. Crabtree

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O2-assay study and its regioselective C-H activation activity by product analysis in catalytic runs.

Original languageEnglish
Pages (from-to)1229-1233
Number of pages5
JournalInorganica Chimica Acta
Volume362
Issue number4
DOIs
Publication statusPublished - Mar 2 2009

Fingerprint

Molecular recognition
Oxygenation
oxygenation
Paramagnetic resonance
Byproducts
Assays
Screening
screening
Chemical activation
catalysts
Oxidation
Electrodes
Catalysts
Water
assembling
activation
oxidation
electrodes
water

Keywords

  • Hydrogen bond

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

In situ dimanganese catalyst for fast screening of molecular recognition catalysts for regioselective oxygenation of an sp3 C-H bond. / Das, Siddhartha; Brudvig, Gary W; Crabtree, Robert H.

In: Inorganica Chimica Acta, Vol. 362, No. 4, 02.03.2009, p. 1229-1233.

Research output: Contribution to journalArticle

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