Abstract
We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O2-assay study and its regioselective C-H activation activity by product analysis in catalytic runs.
| Original language | English |
|---|---|
| Pages (from-to) | 1229-1233 |
| Number of pages | 5 |
| Journal | Inorganica Chimica Acta |
| Volume | 362 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Mar 2 2009 |
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Keywords
- Hydrogen bond
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
In situ dimanganese catalyst for fast screening of molecular recognition catalysts for regioselective oxygenation of an sp3 C-H bond. / Das, Siddhartha; Brudvig, Gary W; Crabtree, Robert H.
In: Inorganica Chimica Acta, Vol. 362, No. 4, 02.03.2009, p. 1229-1233.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - In situ dimanganese catalyst for fast screening of molecular recognition catalysts for regioselective oxygenation of an sp3 C-H bond
AU - Das, Siddhartha
AU - Brudvig, Gary W
AU - Crabtree, Robert H.
PY - 2009/3/2
Y1 - 2009/3/2
N2 - We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O2-assay study and its regioselective C-H activation activity by product analysis in catalytic runs.
AB - We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O2-assay study and its regioselective C-H activation activity by product analysis in catalytic runs.
KW - Hydrogen bond
UR - http://www.scopus.com/inward/record.url?scp=59649091180&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=59649091180&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2008.06.009
DO - 10.1016/j.ica.2008.06.009
M3 - Article
VL - 362
SP - 1229
EP - 1233
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
IS - 4
ER -