In situ multinuclear NMR spectroscopic studies of the thermal decomposition of ammonia borane in solution

Wendy J. Shaw; John C. Linehan; Nathaniel K. Szymczak; David J. Heldebrant; Clem Yonker; Donald M. Camaioni; R. Tom Baker; Tom Autrey

doi:10.1002/anie.200802100

In situ multinuclear NMR spectroscopic studies of the thermal decomposition of ammonia borane in solution

Wendy J. Shaw, John C. Linehan, Nathaniel K. Szymczak, David J. Heldebrant, Clem Yonker, Donald M. Camaioni, R. Tom Baker, Tom Autrey

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

146 Citations (Scopus)

Abstract

(Chemical Equation Presented) Looking to the future: The decomposition in solution of a potential hydrogen-storage compound, ammonia borane (AB), was investigated by in situ ¹¹B NMR spectroscopy and ex situ ¹⁵N NMR spectroscopy. The reaction was found to be second order in AB withan activation barrier of (25 ± 2) kcal mol^-1. The second-order kinetics have implications for the use of solutions containing AB in high concentrations for hydrogen storage.

Original language	English
Pages (from-to)	7493-7496
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	39
DOIs	https://doi.org/10.1002/anie.200802100
Publication status	Published - Sep 15 2008

Keywords

Amine boranes
Hydrogen storage
Kinetics
NMR spectroscopy
Thermolysis

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200802100

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In situ multinuclear NMR spectroscopic studies of the thermal decomposition of ammonia borane in solution. / Shaw, Wendy J.; Linehan, John C.; Szymczak, Nathaniel K.; Heldebrant, David J.; Yonker, Clem; Camaioni, Donald M.; Baker, R. Tom; Autrey, Tom.

In: Angewandte Chemie - International Edition, Vol. 47, No. 39, 15.09.2008, p. 7493-7496.

Research output: Contribution to journal › Article › peer-review

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abstract = "(Chemical Equation Presented) Looking to the future: The decomposition in solution of a potential hydrogen-storage compound, ammonia borane (AB), was investigated by in situ 11B NMR spectroscopy and ex situ 15N NMR spectroscopy. The reaction was found to be second order in AB withan activation barrier of (25 ± 2) kcal mol-1. The second-order kinetics have implications for the use of solutions containing AB in high concentrations for hydrogen storage.",

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AU - Szymczak, Nathaniel K.

AU - Heldebrant, David J.

AU - Yonker, Clem

AU - Camaioni, Donald M.

AU - Baker, R. Tom

AU - Autrey, Tom

PY - 2008/9/15

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AB - (Chemical Equation Presented) Looking to the future: The decomposition in solution of a potential hydrogen-storage compound, ammonia borane (AB), was investigated by in situ 11B NMR spectroscopy and ex situ 15N NMR spectroscopy. The reaction was found to be second order in AB withan activation barrier of (25 ± 2) kcal mol-1. The second-order kinetics have implications for the use of solutions containing AB in high concentrations for hydrogen storage.

KW - Amine boranes

KW - Hydrogen storage

KW - Kinetics

KW - NMR spectroscopy

KW - Thermolysis

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In situ multinuclear NMR spectroscopic studies of the thermal decomposition of ammonia borane in solution

Abstract

Keywords

ASJC Scopus subject areas

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