In-situ spectroscopic studies of rhodium catalyzed production of hydrogen from dimethylamine borane. Homogeneous or heterogeneous catalysis?

Yongsheng Chen, John Fulton, John Linehan, Tom Autrey

Research output: Contribution to journalConference article

24 Citations (Scopus)

Abstract

The DOE has recently issued a Grand Challenge in Hydrogen Storage. The ambitious goals for volumetric and gravimetric densities and the controlled release of H 2 from materials at temperatures below 80°C contained within this Grand Challenge demand the discovery of new materials and catalysts. The chemical and physical properties of amine borane complexes was studied. Transition metal species during the progression of the reaction were observed. The predominant species observed during H 2 evolution did not appear to be colloidal but most likely was composed of 2-6 Rh atoms surrounded by tightly bound external ligands. This result was in contrast to previous conclusions that suggest the mechanism involves a heterogeneous catalyst.

Original languageEnglish
Pages (from-to)972-973
Number of pages2
JournalACS Division of Fuel Chemistry, Preprints
Volume49
Issue number2
Publication statusPublished - Sep 1 2004

ASJC Scopus subject areas

  • Energy(all)

Fingerprint Dive into the research topics of 'In-situ spectroscopic studies of rhodium catalyzed production of hydrogen from dimethylamine borane. Homogeneous or heterogeneous catalysis?'. Together they form a unique fingerprint.

  • Cite this