In Situ Synthesis of Highly Dispersed and Ultrafine Metal Nanoparticles from Chalcogels

Jian Liu; Kai He; Weiqiang Wu; Tze Bin Song; Mercouri G. Kanatzidis

doi:10.1021/jacs.6b13279

In Situ Synthesis of Highly Dispersed and Ultrafine Metal Nanoparticles from Chalcogels

Jian Liu, Kai He, Weiqiang Wu, Tze Bin Song, Mercouri G. Kanatzidis

Northwestern University

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

We report a unique reaction type for facile synthesis of ultrafine and well-dispersed Pt nanoparticles supported on chalcogel surfaces. The nanoparticles are obtained by in situ Pt²⁺ reduction of a chalcogel network formed by the metathesis reaction between K₂PtCl₄ and Na₄SnS₄. The rapid catalytic ability of the chalcogel-supported Pt nanoparticles is demonstrated in a recyclable manner by using 4-nitrophenol reduction as a probe reaction.

Original language	English
Pages (from-to)	2900-2903
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	139
Issue number	8
DOIs	https://doi.org/10.1021/jacs.6b13279
Publication status	Published - Mar 1 2017

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.6b13279

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title = "In Situ Synthesis of Highly Dispersed and Ultrafine Metal Nanoparticles from Chalcogels",

abstract = "We report a unique reaction type for facile synthesis of ultrafine and well-dispersed Pt nanoparticles supported on chalcogel surfaces. The nanoparticles are obtained by in situ Pt2+ reduction of a chalcogel network formed by the metathesis reaction between K2PtCl4 and Na4SnS4. The rapid catalytic ability of the chalcogel-supported Pt nanoparticles is demonstrated in a recyclable manner by using 4-nitrophenol reduction as a probe reaction.",

author = "Jian Liu and Kai He and Weiqiang Wu and Song, {Tze Bin} and Kanatzidis, {Mercouri G.}",

note = "Funding Information: This work was supported as part of the ANSER Center, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under award no. DE-SC0001059.",

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AU - Liu, Jian

AU - He, Kai

AU - Wu, Weiqiang

AU - Song, Tze Bin

AU - Kanatzidis, Mercouri G.

N1 - Funding Information: This work was supported as part of the ANSER Center, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under award no. DE-SC0001059.

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AB - We report a unique reaction type for facile synthesis of ultrafine and well-dispersed Pt nanoparticles supported on chalcogel surfaces. The nanoparticles are obtained by in situ Pt2+ reduction of a chalcogel network formed by the metathesis reaction between K2PtCl4 and Na4SnS4. The rapid catalytic ability of the chalcogel-supported Pt nanoparticles is demonstrated in a recyclable manner by using 4-nitrophenol reduction as a probe reaction.

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