In situ XAFS and NMR study of rhodium-catalyzed dehydrogenation of dimethylamine borane

Yongsheng Chen, John L. Fulton, John Linehan, Tom Autrey

Research output: Contribution to journalArticle

186 Citations (Scopus)

Abstract

In situ X-ray absorption fine structure spectroscopy (XAFS) and 11B NMR were used to study the rhodium-catalyzed dimerization reaction of dimethylaminoborane, (CH3)2NHBH3 or DMAB. XAFS spectra show that the active form of the rhodium catalyst is most likely composed of a six-atom Rh core surrounded by tightly bound external ligands. NMR results show the presence of monomeric dimethylamine borane (CH3)2NBH2, providing evidence that hydrogen formation from the homogeneous Rh species occurs by an intramolecular pathway. This is in contrast to thermal pathways that involve intermolecular B-N concurrent with hydrogen formation. This work shows that in situ XAFS spectroscopy offers a unique experimental tool to differentiate between heterogeneous and homogeneous catalysis.

Original languageEnglish
Pages (from-to)3254-3255
Number of pages2
JournalJournal of the American Chemical Society
Volume127
Issue number10
DOIs
Publication statusPublished - Mar 16 2005

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X ray absorption fine structure spectroscopy
Boranes
Rhodium
Dehydrogenation
Spectrum Analysis
Magnetic Resonance Spectroscopy
Nuclear magnetic resonance
X-Rays
Hydrogen
Dimerization
Catalysis
Hot Temperature
Ligands
Spectroscopy
Atoms
Catalysts
dimethylamine

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

In situ XAFS and NMR study of rhodium-catalyzed dehydrogenation of dimethylamine borane. / Chen, Yongsheng; Fulton, John L.; Linehan, John; Autrey, Tom.

In: Journal of the American Chemical Society, Vol. 127, No. 10, 16.03.2005, p. 3254-3255.

Research output: Contribution to journalArticle

Chen, Yongsheng ; Fulton, John L. ; Linehan, John ; Autrey, Tom. / In situ XAFS and NMR study of rhodium-catalyzed dehydrogenation of dimethylamine borane. In: Journal of the American Chemical Society. 2005 ; Vol. 127, No. 10. pp. 3254-3255.
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