Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework

Nathan L. Strutt, David Fairen-Jimenez, Julien Iehl, Marianne B. Lalonde, Randall Q. Snurr, Omar K. Farha, Joseph T Hupp, J. Fraser Stoddart

Research output: Contribution to journalArticle

149 Citations (Scopus)

Abstract

An efficient synthetic route to an A1/A2-difunctionalized pillar[5]arene containing resolvable planar chirality has been developed and the arene employed as a strut in the synthesis of P5A-MOF-1, which has been demonstrated by X-ray powder diffraction analysis-supported by modeling-to be isoreticular with MOF-5. This metal-organic framework has an active domain that expresses good and selective uptake of neutral and positively charged electron-poor aromatic guests, which effect color changes of the cubic crystals from faint yellow to deep orange, arising from charge transfer between the guests and active domain of P5A-MOF-1.

Original languageEnglish
Pages (from-to)17436-17439
Number of pages4
JournalJournal of the American Chemical Society
Volume134
Issue number42
DOIs
Publication statusPublished - Oct 24 2012

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Powder Diffraction
Chirality
Struts
varespladib methyl
X-Ray Diffraction
X ray powder diffraction
Charge transfer
Color
Metals
Electrons
Crystals
pillar(5)arene

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Strutt, N. L., Fairen-Jimenez, D., Iehl, J., Lalonde, M. B., Snurr, R. Q., Farha, O. K., ... Stoddart, J. F. (2012). Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework. Journal of the American Chemical Society, 134(42), 17436-17439. https://doi.org/10.1021/ja3082523

Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework. / Strutt, Nathan L.; Fairen-Jimenez, David; Iehl, Julien; Lalonde, Marianne B.; Snurr, Randall Q.; Farha, Omar K.; Hupp, Joseph T; Stoddart, J. Fraser.

In: Journal of the American Chemical Society, Vol. 134, No. 42, 24.10.2012, p. 17436-17439.

Research output: Contribution to journalArticle

Strutt, NL, Fairen-Jimenez, D, Iehl, J, Lalonde, MB, Snurr, RQ, Farha, OK, Hupp, JT & Stoddart, JF 2012, 'Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework', Journal of the American Chemical Society, vol. 134, no. 42, pp. 17436-17439. https://doi.org/10.1021/ja3082523
Strutt NL, Fairen-Jimenez D, Iehl J, Lalonde MB, Snurr RQ, Farha OK et al. Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework. Journal of the American Chemical Society. 2012 Oct 24;134(42):17436-17439. https://doi.org/10.1021/ja3082523
Strutt, Nathan L. ; Fairen-Jimenez, David ; Iehl, Julien ; Lalonde, Marianne B. ; Snurr, Randall Q. ; Farha, Omar K. ; Hupp, Joseph T ; Stoddart, J. Fraser. / Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework. In: Journal of the American Chemical Society. 2012 ; Vol. 134, No. 42. pp. 17436-17439.
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