Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests

Chung Wei Kung; Kenichi Otake; Cassandra T. Buru; Subhadip Goswami; Yuexing Cui; Joseph T Hupp; Alexander M. Spokoyny; Omar K. Farha

doi:10.1021/jacs.8b00605

Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests

Chung Wei Kung, Kenichi Otake, Cassandra T. Buru, Subhadip Goswami, Yuexing Cui, Joseph T Hupp, Alexander M. Spokoyny, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article

47 Citations (Scopus)

Abstract

Nickel(IV) bis(dicarbollide) is incorporated in a zirconium-based metal-organic framework (MOF), NU-1000, to create an electrically conductive MOF with mesoporosity. All the nickel bis(dicarbollide) units are located as guest molecules in the microporous channels of NU-1000, which permits the further incorporation of other active species in the remaining mesopores. For demonstration, manganese oxide is installed on the nodes of the electrically conductive MOF. The electrochemically addressable fraction and specific capacitance of the manganese oxide in the conductive framework are more than 10 times higher than those of the manganese oxide in the parent MOF.

Original language	English
Pages (from-to)	3871-3875
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	140
Issue number	11
DOIs	https://doi.org/10.1021/jacs.8b00605
Publication status	Published - Mar 21 2018

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ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Cite this

Kung, C. W., Otake, K., Buru, C. T., Goswami, S., Cui, Y., Hupp, J. T., Spokoyny, A. M., & Farha, O. K. (2018). Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests. Journal of the American Chemical Society, 140(11), 3871-3875. https://doi.org/10.1021/jacs.8b00605

Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests. / Kung, Chung Wei; Otake, Kenichi; Buru, Cassandra T.; Goswami, Subhadip; Cui, Yuexing; Hupp, Joseph T; Spokoyny, Alexander M.; Farha, Omar K.

In: Journal of the American Chemical Society, Vol. 140, No. 11, 21.03.2018, p. 3871-3875.

Research output: Contribution to journal › Article

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Access to Document

10.1021/jacs.8b00605