Abstract
Nickel(IV) bis(dicarbollide) is incorporated in a zirconium-based metal-organic framework (MOF), NU-1000, to create an electrically conductive MOF with mesoporosity. All the nickel bis(dicarbollide) units are located as guest molecules in the microporous channels of NU-1000, which permits the further incorporation of other active species in the remaining mesopores. For demonstration, manganese oxide is installed on the nodes of the electrically conductive MOF. The electrochemically addressable fraction and specific capacitance of the manganese oxide in the conductive framework are more than 10 times higher than those of the manganese oxide in the parent MOF.
| Original language | English |
|---|---|
| Pages (from-to) | 3871-3875 |
| Number of pages | 5 |
| Journal | Journal of the American Chemical Society |
| Volume | 140 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Mar 21 2018 |
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ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests. / Kung, Chung Wei; Otake, Kenichi; Buru, Cassandra T.; Goswami, Subhadip; Cui, Yuexing; Hupp, Joseph T; Spokoyny, Alexander M.; Farha, Omar K.
In: Journal of the American Chemical Society, Vol. 140, No. 11, 21.03.2018, p. 3871-3875.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests
AU - Kung, Chung Wei
AU - Otake, Kenichi
AU - Buru, Cassandra T.
AU - Goswami, Subhadip
AU - Cui, Yuexing
AU - Hupp, Joseph T
AU - Spokoyny, Alexander M.
AU - Farha, Omar K.
PY - 2018/3/21
Y1 - 2018/3/21
N2 - Nickel(IV) bis(dicarbollide) is incorporated in a zirconium-based metal-organic framework (MOF), NU-1000, to create an electrically conductive MOF with mesoporosity. All the nickel bis(dicarbollide) units are located as guest molecules in the microporous channels of NU-1000, which permits the further incorporation of other active species in the remaining mesopores. For demonstration, manganese oxide is installed on the nodes of the electrically conductive MOF. The electrochemically addressable fraction and specific capacitance of the manganese oxide in the conductive framework are more than 10 times higher than those of the manganese oxide in the parent MOF.
AB - Nickel(IV) bis(dicarbollide) is incorporated in a zirconium-based metal-organic framework (MOF), NU-1000, to create an electrically conductive MOF with mesoporosity. All the nickel bis(dicarbollide) units are located as guest molecules in the microporous channels of NU-1000, which permits the further incorporation of other active species in the remaining mesopores. For demonstration, manganese oxide is installed on the nodes of the electrically conductive MOF. The electrochemically addressable fraction and specific capacitance of the manganese oxide in the conductive framework are more than 10 times higher than those of the manganese oxide in the parent MOF.
UR - http://www.scopus.com/inward/record.url?scp=85044389935&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85044389935&partnerID=8YFLogxK
U2 - 10.1021/jacs.8b00605
DO - 10.1021/jacs.8b00605
M3 - Article
VL - 140
SP - 3871
EP - 3875
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 11
ER -