Increasing the aromatic selectivity of quinoline hydrogenolysis using Pd/MOx-Al2O3

Mark Bachrach, Natalia Morlanes-Sanchez, Christian P. Canlas, Jeffrey T. Miller, Tobin J Marks, Justin M Notestein

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Catalysts consisting of Pd nanoparticles supported on highly dispersed TiOx-Al2O3, TaOx-Al2O3, and MoOx-Al2O3 are studied for catalytic quinoline hydrogenation and selective C-N bond cleavage at 275°C and 20 bar H2. The Pd/MOx-Al2O3 materials exhibit significantly greater aromatic product selectivity and thus 10-15 % less required H2 for a given level of denitrogenation relative to an unmodified Pd/Al2O3 catalyst.

Original languageEnglish
Pages (from-to)1832-1838
Number of pages7
JournalCatalysis Letters
Volume144
Issue number11
DOIs
Publication statusPublished - 2014

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Hydrogenolysis
Catalyst selectivity
Catalysts
Hydrogenation
Nanoparticles
quinoline

Keywords

  • C-N bond cleavage
  • Hydrodenitrogenation
  • Molybdenum
  • Palladium
  • Quinoline
  • Supported metal oxides
  • Tantalum
  • Titanium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Increasing the aromatic selectivity of quinoline hydrogenolysis using Pd/MOx-Al2O3. / Bachrach, Mark; Morlanes-Sanchez, Natalia; Canlas, Christian P.; Miller, Jeffrey T.; Marks, Tobin J; Notestein, Justin M.

In: Catalysis Letters, Vol. 144, No. 11, 2014, p. 1832-1838.

Research output: Contribution to journalArticle

Bachrach, Mark ; Morlanes-Sanchez, Natalia ; Canlas, Christian P. ; Miller, Jeffrey T. ; Marks, Tobin J ; Notestein, Justin M. / Increasing the aromatic selectivity of quinoline hydrogenolysis using Pd/MOx-Al2O3. In: Catalysis Letters. 2014 ; Vol. 144, No. 11. pp. 1832-1838.
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