TY - JOUR
T1 - Inducing desorption of organic molecules with a scanning tunneling microscope
T2 - theory and experiments
AU - Alavi, Saman
AU - Rousseau, Roger
AU - Patitsas, S. N.
AU - Lopinski, Gregory P.
AU - Wolkow, Robert A.
AU - Seideman, Tamar
PY - 2000/12/18
Y1 - 2000/12/18
N2 - The STM-induced desorption of benzene from Si(100) was experimentally and theoretically studied. A striking threshold in the bias dependence and relatively high yields under mild conditions was observed. A theoretical model rationalized the observations in terms of transient ionization of a π state of the molecule and generaized the findings to predict the behavior of different classes of organic adsorbates under similar conditions.
AB - The STM-induced desorption of benzene from Si(100) was experimentally and theoretically studied. A striking threshold in the bias dependence and relatively high yields under mild conditions was observed. A theoretical model rationalized the observations in terms of transient ionization of a π state of the molecule and generaized the findings to predict the behavior of different classes of organic adsorbates under similar conditions.
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U2 - 10.1103/PhysRevLett.85.5372
DO - 10.1103/PhysRevLett.85.5372
M3 - Article
C2 - 11135999
AN - SCOPUS:0034506795
VL - 85
SP - 5372
EP - 5375
JO - Physical Review Letters
JF - Physical Review Letters
SN - 0031-9007
IS - 25
ER -