Influence of cryptands and crown ethers on ion transport and vibrational spectra of polymer-salt complexes

Kate E. Doan, Bruce J. Heyen, Mark A Ratner, D. F. Shriver

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Complex impedance data demonstrate that addition of 2.2.2-cryptand increases the conductivity of NaSO3CH3 in amorphous poly(ethylene oxide) (aPEO) but decreases that of NaSO3CF3 in aPEO. Vibrational spectroscopic and X-ray diffraction measurements indicate that the influence of 2.2.2-cryptand is to dissolve crystallites of NaSO3CH3 into the polymer phase. The decrease in conductivity for NaSO3CF3-aPEO upon addition of 2.2.2-cryptand correlates with the precipitation of a crystalline phase, presumably [Na:2.2.2][SO3CF3].

Original languageEnglish
Pages (from-to)539-545
Number of pages7
JournalChemistry of Materials
Volume2
Issue number5
Publication statusPublished - 1990

ASJC Scopus subject areas

  • Materials Chemistry
  • Materials Science(all)

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