Influence of shell thickness on the performance of light-emitting devices based on CdSe/Zn 1- X Cd x S core/shell heterostructured quantum dots

Jaehoon Lim; Byeong Guk Jeong; Myeongjin Park; Jai Kyeong Kim; Jeffrey M. Pietryga; Young Shin Park; Victor I. Klimov; Changhee Lee; Doh C. Lee; Wan Ki Bae

doi:10.1002/adma.201403620

Influence of shell thickness on the performance of light-emitting devices based on CdSe/Zn 1- X Cd x S core/shell heterostructured quantum dots

Jaehoon Lim, Byeong Guk Jeong, Myeongjin Park, Jai Kyeong Kim, Jeffrey M. Pietryga, Young Shin Park, Victor I. Klimov, Changhee Lee, Doh C. Lee, Wan Ki Bae

Los Alamos National Laboratory

Research output: Contribution to journal › Article › peer-review

161 Citations (Scopus)

Abstract

The rapid advance and growth of the display industry has provided an impetus for the development of novel emissive materials for high-energy-efficiency light-emitting diodes (LED). Quantum dots (QD) offer narrow, size-tunable emission over the full visible wavelength region, and consequently have received particular attention as a class of high-color-purity fluorophores. However, PL lifetimes drastically decrease when QDs are assembled into compact films and decrease further within the actual devices, with a severity noticeably dependent on shell thickness. Intriguingly, this tendency is markedly similar to absolute PL QYs measured on the same samples using an integrating sphere spectrometer. Spectroscopic analysis of the QLEDs demonstrates the influence of nonradiative recombination processes on the overall device characteristics.

Original language	English
Pages (from-to)	8034-8040
Number of pages	7
Journal	Advanced Materials
Volume	26
Issue number	47
DOIs	https://doi.org/10.1002/adma.201403620
Publication status	Published - Jan 1 2014

ASJC Scopus subject areas

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

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Influence of shell thickness on the performance of light-emitting devices based on CdSe/Zn 1- X Cd x S core/shell heterostructured quantum dots. / Lim, Jaehoon; Jeong, Byeong Guk; Park, Myeongjin; Kim, Jai Kyeong; Pietryga, Jeffrey M.; Park, Young Shin; Klimov, Victor I.; Lee, Changhee; Lee, Doh C.; Bae, Wan Ki.

In: Advanced Materials, Vol. 26, No. 47, 01.01.2014, p. 8034-8040.

Research output: Contribution to journal › Article › peer-review

Lim, Jaehoon ; Jeong, Byeong Guk ; Park, Myeongjin ; Kim, Jai Kyeong ; Pietryga, Jeffrey M. ; Park, Young Shin ; Klimov, Victor I. ; Lee, Changhee ; Lee, Doh C. ; Bae, Wan Ki. / Influence of shell thickness on the performance of light-emitting devices based on CdSe/Zn 1- X Cd x S core/shell heterostructured quantum dots. In: Advanced Materials. 2014 ; Vol. 26, No. 47. pp. 8034-8040.

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abstract = "The rapid advance and growth of the display industry has provided an impetus for the development of novel emissive materials for high-energy-efficiency light-emitting diodes (LED). Quantum dots (QD) offer narrow, size-tunable emission over the full visible wavelength region, and consequently have received particular attention as a class of high-color-purity fluorophores. However, PL lifetimes drastically decrease when QDs are assembled into compact films and decrease further within the actual devices, with a severity noticeably dependent on shell thickness. Intriguingly, this tendency is markedly similar to absolute PL QYs measured on the same samples using an integrating sphere spectrometer. Spectroscopic analysis of the QLEDs demonstrates the influence of nonradiative recombination processes on the overall device characteristics.",

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