Inorganic-organic hybrid materials based on keggin type polyoxometalates and organic polyammonium cations

Maxym Vasylyev, Ronit Popovitz-Biro, Linda J.W. Shimon, Ronny Neumann

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)

Abstract

Co-crystallization of a tri-ammonium cation with short and somewhat flexible 'arms', [N,N,N-tris[2-(dimethylamino)ethyl]-1,3,5-benzenetricarboxamide]3+, with a polyoxometalate trianion, PW12O403-, yielded an insoluble channeled or microporous structure. The polyoxometalate clusters are arranged in a layered and zig-zag fashion along the xy plane. Looking along the x-axis, channels of a dimension of ∼3.5 × ∼6.5 Å are observed. It was found that C-H⋯O bonds aided in determining the crystal packing by providing directionality to the anion-cation interaction. On the other hand the co-crystallization of a tetraammonium cation with an extended and rigid tetrahedral configuration, 1,3,5,7-tetrakis{4-[(E)-2(N-methylpyridinium-4-yl)vinyl]phenyl adamantane tetraiodide, with a polyoxometalate tetracation, SiW12O 404-, yielded a lamellar structure with alternating layers with spacing of 16.6 Å of the inorganic-organic hybrid material.

Original languageEnglish
Pages (from-to)27-35
Number of pages9
JournalJournal of Molecular Structure
Volume656
Issue number1-3
DOIs
Publication statusPublished - Aug 27 2003

Keywords

  • Ammonium cation
  • Lamellar structure
  • Microporous material
  • Polyoxometalate

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Inorganic-organic hybrid materials based on keggin type polyoxometalates and organic polyammonium cations'. Together they form a unique fingerprint.

Cite this