Instability, intermixing and electronic structure at the epitaxial LaAlO3SrTiO3(001) heterojunction

S. A. Chambers, M. H. Engelhard, V. Shutthanandan, Z. Zhu, T. C. Droubay, L. Qiao, P. V. Sushko, T. Feng, H. D. Lee, T. Gustafsson, Eric Garfunkel, A. B. Shah, J. M. Zuo, Q. M. Ramasse

Research output: Contribution to journalArticle

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Abstract

The question of stability against diffusional mixing at the prototypical LaAlO3SrTiO3(001) interface is explored using a multi-faceted experimental and theoretical approach. We combine analytical methods with a range of sensitivities to elemental concentrations and spatial separations to investigate interfaces grown using on-axis pulsed laser deposition. We also employ computational modeling based on the density function theory as well as classical force fields to explore the energetic stability of a wide variety of intermixed atomic configurations relative to the idealized, atomically abrupt model. Statistical analysis of the calculated energies for the various configurations is used to elucidate the relative thermodynamic stability of intermixed and abrupt configurations. We find that on both experimental and theoretical fronts, the tendency toward intermixing is very strong. We have also measured and calculated key electronic properties such as potential energy gradients and valence band discontinuity at the interface. We find no measurable electric field in either the LaAlO3 or SrTiO 3, and that the valence band offset is near zero, partitioning the band discontinuity almost entirely to the conduction band edge. Significantly, we find it is not possible to account for these electronic properties theoretically without including extensive intermixing in our physical model of the interface. The atomic configurations which give the greatest electrostatic stability are those that eliminate the interface dipole by intermixing, calling into question the conventional explanation for conductivity at this interfaceelectronic reconstruction. Rather, evidence is presented for La indiffusion and doping of the SrTiO3 below the interface as being the cause of the observed conductivity.

Original languageEnglish
Pages (from-to)317-352
Number of pages36
JournalSurface Science Reports
Volume65
Issue number10-12
DOIs
Publication statusPublished - Oct 2010

Fingerprint

Electronic structure
Heterojunctions
heterojunctions
electronic structure
Valence bands
Electronic properties
Pulsed laser deposition
configurations
Potential energy
Conduction bands
Probability density function
Electrostatics
Statistical methods
discontinuity
Thermodynamic stability
Electric fields
Doping (additives)
valence
conductivity
electronics

ASJC Scopus subject areas

  • Surfaces and Interfaces
  • Condensed Matter Physics
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Metals and Alloys

Cite this

Chambers, S. A., Engelhard, M. H., Shutthanandan, V., Zhu, Z., Droubay, T. C., Qiao, L., ... Ramasse, Q. M. (2010). Instability, intermixing and electronic structure at the epitaxial LaAlO3SrTiO3(001) heterojunction. Surface Science Reports, 65(10-12), 317-352. https://doi.org/10.1016/j.surfrep.2010.09.001

Instability, intermixing and electronic structure at the epitaxial LaAlO3SrTiO3(001) heterojunction. / Chambers, S. A.; Engelhard, M. H.; Shutthanandan, V.; Zhu, Z.; Droubay, T. C.; Qiao, L.; Sushko, P. V.; Feng, T.; Lee, H. D.; Gustafsson, T.; Garfunkel, Eric; Shah, A. B.; Zuo, J. M.; Ramasse, Q. M.

In: Surface Science Reports, Vol. 65, No. 10-12, 10.2010, p. 317-352.

Research output: Contribution to journalArticle

Chambers, SA, Engelhard, MH, Shutthanandan, V, Zhu, Z, Droubay, TC, Qiao, L, Sushko, PV, Feng, T, Lee, HD, Gustafsson, T, Garfunkel, E, Shah, AB, Zuo, JM & Ramasse, QM 2010, 'Instability, intermixing and electronic structure at the epitaxial LaAlO3SrTiO3(001) heterojunction', Surface Science Reports, vol. 65, no. 10-12, pp. 317-352. https://doi.org/10.1016/j.surfrep.2010.09.001
Chambers, S. A. ; Engelhard, M. H. ; Shutthanandan, V. ; Zhu, Z. ; Droubay, T. C. ; Qiao, L. ; Sushko, P. V. ; Feng, T. ; Lee, H. D. ; Gustafsson, T. ; Garfunkel, Eric ; Shah, A. B. ; Zuo, J. M. ; Ramasse, Q. M. / Instability, intermixing and electronic structure at the epitaxial LaAlO3SrTiO3(001) heterojunction. In: Surface Science Reports. 2010 ; Vol. 65, No. 10-12. pp. 317-352.
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AU - Zhu, Z.

AU - Droubay, T. C.

AU - Qiao, L.

AU - Sushko, P. V.

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AU - Lee, H. D.

AU - Gustafsson, T.

AU - Garfunkel, Eric

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