Intercalation of polyfuran in FeOCl.

C. G. Wu, H. O. Marcy, D. C. DeGroot, J. L. Schindler, C. R. Kannewurf, W. Y. Leung, M. Benz, E. LeGoff, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

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Abstract

The intercalation of polyfuran, by in-situ intercalative oxidative polymerization of terfuran in FeOCl is reported. The intercalation reaction proceeds to completion in methanol in a sealed tube at 100 °C. The resulting compound, polyfuran/FeOCl (I), is crystalline. An interlayer expansion of ≈7.7 A ̊ is observed upon intercalation. The formation of polyfuran in the interlayer space of the host material was confirmed by FTIR spectroscopy and by isolation of the polymers from the host. Tetrafuran could not be intercalated completely under the conditions employed. Electrical conductivity and thermoelectric power data from pressed pellets of (I) are reported and the results are compared with other FeOCl intercalated polymers. X-ray diffraction, magnetic, infrared spectroscopic and scanning and transmission electron microscopic characterization of (I) are reported.

Original languageEnglish
Pages (from-to)797-803
Number of pages7
JournalSynthetic Metals
Volume41
Issue number3
DOIs
Publication statusPublished - May 6 1991

Fingerprint

Intercalation
intercalation
interlayers
Polymers
Thermoelectric power
polymers
pellets
Methanol
isolation
polymerization
methyl alcohol
Polymerization
Spectroscopy
tubes
Crystalline materials
Infrared radiation
Scanning
X ray diffraction
electrical resistivity
expansion

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Wu, C. G., Marcy, H. O., DeGroot, D. C., Schindler, J. L., Kannewurf, C. R., Leung, W. Y., ... Kanatzidis, M. G. (1991). Intercalation of polyfuran in FeOCl. Synthetic Metals, 41(3), 797-803. https://doi.org/10.1016/0379-6779(91)91500-A

Intercalation of polyfuran in FeOCl. / Wu, C. G.; Marcy, H. O.; DeGroot, D. C.; Schindler, J. L.; Kannewurf, C. R.; Leung, W. Y.; Benz, M.; LeGoff, E.; Kanatzidis, Mercouri G.

In: Synthetic Metals, Vol. 41, No. 3, 06.05.1991, p. 797-803.

Research output: Contribution to journalArticle

Wu, CG, Marcy, HO, DeGroot, DC, Schindler, JL, Kannewurf, CR, Leung, WY, Benz, M, LeGoff, E & Kanatzidis, MG 1991, 'Intercalation of polyfuran in FeOCl.', Synthetic Metals, vol. 41, no. 3, pp. 797-803. https://doi.org/10.1016/0379-6779(91)91500-A
Wu CG, Marcy HO, DeGroot DC, Schindler JL, Kannewurf CR, Leung WY et al. Intercalation of polyfuran in FeOCl. Synthetic Metals. 1991 May 6;41(3):797-803. https://doi.org/10.1016/0379-6779(91)91500-A
Wu, C. G. ; Marcy, H. O. ; DeGroot, D. C. ; Schindler, J. L. ; Kannewurf, C. R. ; Leung, W. Y. ; Benz, M. ; LeGoff, E. ; Kanatzidis, Mercouri G. / Intercalation of polyfuran in FeOCl. In: Synthetic Metals. 1991 ; Vol. 41, No. 3. pp. 797-803.
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AB - The intercalation of polyfuran, by in-situ intercalative oxidative polymerization of terfuran in FeOCl is reported. The intercalation reaction proceeds to completion in methanol in a sealed tube at 100 °C. The resulting compound, polyfuran/FeOCl (I), is crystalline. An interlayer expansion of ≈7.7 A ̊ is observed upon intercalation. The formation of polyfuran in the interlayer space of the host material was confirmed by FTIR spectroscopy and by isolation of the polymers from the host. Tetrafuran could not be intercalated completely under the conditions employed. Electrical conductivity and thermoelectric power data from pressed pellets of (I) are reported and the results are compared with other FeOCl intercalated polymers. X-ray diffraction, magnetic, infrared spectroscopic and scanning and transmission electron microscopic characterization of (I) are reported.

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