Interconversion of CO2/H2 and Formic Acid Under Mild Conditions in Water. Ligand Design for Effective Catalysis

Wan Hui Wang, Yuichiro Himeda, James T. Muckerman, Etsuko Fujita

Research output: Chapter in Book/Report/Conference proceedingChapter

27 Citations (Scopus)

Abstract

Recent significant progress in the homogeneous catalytic hydrogenation of CO2 to formate (the conjugate base of formic acid) and dehydrogenation of formic acid in various solvents including water is summarized. While formic acid is not the perfect H2 storage solution, many researchers consider it better than other methods at this time because the interconversion of CO2 and formic acid can take place cleanly to form H2 without detectable CO under mild conditions. In this chapter, we explain how inspirations from biological systems guide us to design homogeneous transition-metal catalysts for carrying out the interconversion of CO2 and formate under ambient conditions in environmentally benign and economically desirable water solvent.

Original languageEnglish
Title of host publicationAdvances in Inorganic Chemistry
PublisherAcademic Press Inc
Pages189-222
Number of pages34
DOIs
Publication statusPublished - 2014

Publication series

NameAdvances in Inorganic Chemistry
Volume66
ISSN (Print)0898-8838

Keywords

  • Bioinspired catalysts
  • Dehydrogenation of formic acid
  • Ir complexes
  • Proton-responsive ligands

ASJC Scopus subject areas

  • Inorganic Chemistry

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    Wang, W. H., Himeda, Y., Muckerman, J. T., & Fujita, E. (2014). Interconversion of CO2/H2 and Formic Acid Under Mild Conditions in Water. Ligand Design for Effective Catalysis. In Advances in Inorganic Chemistry (pp. 189-222). (Advances in Inorganic Chemistry; Vol. 66). Academic Press Inc. https://doi.org/10.1016/B978-0-12-420221-4.00006-8