Abstract
The design, synthesis, characterization, and understanding of new molecular and macromolecular substances with "metal-like" electrical properties represents an active research area at the interface of chemistry, physics, and materials science. An important, long-range goal in this field of "materials by design" is to construct supermolecular assemblies which exhibit preordained collective phenomena by virtue of "engineered" interactions between molecular building blocks. In this review, such a class of designed materials is discussed which, in addition, bridges the gap between molecular and polymeric conductors: assemblies of electrically conductive metallomacrocycles. It is seen that efforts to rationally construct stacked metal-like molecular arrays lead logically to structure-enforced macromolecular assemblies of covalently linked molecular subunits. Typical building blocks are robust, chemically versatile metallophthalocyanines. The electrical, optical, and magnetic properties of these metallomacrocyclic assemblies and the fragments thereof, provide fundamental information on the connections between local atomic-scale architecture, electronic structure, and the macroscopic collective properties of the bulk solid.
| Original language | English |
|---|---|
| Pages (from-to) | 857-879 |
| Number of pages | 23 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 29 |
| Issue number | 8 |
| Publication status | Published - Aug 1990 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Interfaces between molecular and polymeric "metals" : Electrically conductive, structure-enforced assemblies of metallomacrocycles. / Marks, Tobin J.
In: Angewandte Chemie - International Edition, Vol. 29, No. 8, 08.1990, p. 857-879.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Interfaces between molecular and polymeric "metals"
T2 - Electrically conductive, structure-enforced assemblies of metallomacrocycles
AU - Marks, Tobin J
PY - 1990/8
Y1 - 1990/8
N2 - The design, synthesis, characterization, and understanding of new molecular and macromolecular substances with "metal-like" electrical properties represents an active research area at the interface of chemistry, physics, and materials science. An important, long-range goal in this field of "materials by design" is to construct supermolecular assemblies which exhibit preordained collective phenomena by virtue of "engineered" interactions between molecular building blocks. In this review, such a class of designed materials is discussed which, in addition, bridges the gap between molecular and polymeric conductors: assemblies of electrically conductive metallomacrocycles. It is seen that efforts to rationally construct stacked metal-like molecular arrays lead logically to structure-enforced macromolecular assemblies of covalently linked molecular subunits. Typical building blocks are robust, chemically versatile metallophthalocyanines. The electrical, optical, and magnetic properties of these metallomacrocyclic assemblies and the fragments thereof, provide fundamental information on the connections between local atomic-scale architecture, electronic structure, and the macroscopic collective properties of the bulk solid.
AB - The design, synthesis, characterization, and understanding of new molecular and macromolecular substances with "metal-like" electrical properties represents an active research area at the interface of chemistry, physics, and materials science. An important, long-range goal in this field of "materials by design" is to construct supermolecular assemblies which exhibit preordained collective phenomena by virtue of "engineered" interactions between molecular building blocks. In this review, such a class of designed materials is discussed which, in addition, bridges the gap between molecular and polymeric conductors: assemblies of electrically conductive metallomacrocycles. It is seen that efforts to rationally construct stacked metal-like molecular arrays lead logically to structure-enforced macromolecular assemblies of covalently linked molecular subunits. Typical building blocks are robust, chemically versatile metallophthalocyanines. The electrical, optical, and magnetic properties of these metallomacrocyclic assemblies and the fragments thereof, provide fundamental information on the connections between local atomic-scale architecture, electronic structure, and the macroscopic collective properties of the bulk solid.
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M3 - Article
VL - 29
SP - 857
EP - 879
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 8
ER -