Interfacial electron transfer into functionalized crystalline polyoxotitanate nanoclusters

Robert C. Snoeberger, Karin J. Young, Jiji Tang, Laura J. Allen, Robert H. Crabtree, Gary W. Brudvig, Philip Coppens, Victor S. Batista, Jason B. Benedict

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54 Citations (Scopus)

Abstract

Interfacial electron transfer (IET) between a chromophore and a semiconductor nanoparticle is one of the key processes in a dye-sensitized solar cell. Theoretical simulations of the electron transfer in polyoxotitanate nanoclusters Ti 17O 24(OPr i) 20 (Ti 17) functionalized with four p-nitrophenyl acetylacetone (NPA-H) adsorbates, of which the atomic structure has been fully established by X-ray diffraction measurements, are presented. Complementary experimental information showing IET has been obtained by EPR spectroscopy. Evolution of the time-dependent photoexcited electron during the initial 5 fs after instantaneous excitation to the NPA LUMO + 1 has been evaluated. Evidence for delocalization of the excitation over multiple chromophores after excitation to the NPA LUMO + 2 state on a 15 fs time scale is also obtained. While chromophores are generally considered electronically isolated with respect to neighboring sensitizers, our calculations show that this is not necessarily the case. The present work is the most comprehensive study to date of a sensitized semiconductor nanoparticle in which the structure of the surface and the mode of molecular adsorption are precisely defined.

Original languageEnglish
Pages (from-to)8911-8917
Number of pages7
JournalJournal of the American Chemical Society
Volume134
Issue number21
DOIs
Publication statusPublished - May 30 2012

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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    Snoeberger, R. C., Young, K. J., Tang, J., Allen, L. J., Crabtree, R. H., Brudvig, G. W., Coppens, P., Batista, V. S., & Benedict, J. B. (2012). Interfacial electron transfer into functionalized crystalline polyoxotitanate nanoclusters. Journal of the American Chemical Society, 134(21), 8911-8917. https://doi.org/10.1021/ja301238t