Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes

Ryan Trovitch, Kevin D. John, Richard L. Martin, Stephen J. Obrey, Brian L. Scott, Alfred P. Sattelberger, R. Thomas Baker

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Addition of PMe3 to Mo2(allyl)4 afforded Mo2(allyl)4(PMe3)2, in which two of the allyl groups adopt an unprecedented μ21, η3 bonding mode; theoretical studies elucidate the roles of the σ- and π-donor ligands in the interplay of metal-allyl and metal-metal bonding.

Original languageEnglish
Pages (from-to)4206-4208
Number of pages3
JournalChemical Communications
Issue number28
DOIs
Publication statusPublished - 2009

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Metals
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ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Trovitch, R., John, K. D., Martin, R. L., Obrey, S. J., Scott, B. L., Sattelberger, A. P., & Baker, R. T. (2009). Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes. Chemical Communications, (28), 4206-4208. https://doi.org/10.1039/b908032e

Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes. / Trovitch, Ryan; John, Kevin D.; Martin, Richard L.; Obrey, Stephen J.; Scott, Brian L.; Sattelberger, Alfred P.; Baker, R. Thomas.

In: Chemical Communications, No. 28, 2009, p. 4206-4208.

Research output: Contribution to journalArticle

Trovitch, R, John, KD, Martin, RL, Obrey, SJ, Scott, BL, Sattelberger, AP & Baker, RT 2009, 'Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes', Chemical Communications, no. 28, pp. 4206-4208. https://doi.org/10.1039/b908032e
Trovitch, Ryan ; John, Kevin D. ; Martin, Richard L. ; Obrey, Stephen J. ; Scott, Brian L. ; Sattelberger, Alfred P. ; Baker, R. Thomas. / Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes. In: Chemical Communications. 2009 ; No. 28. pp. 4206-4208.
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