Intramolecular hydrogen bonding as a synthetic tool to induce chemical selectivity in acid catalyzed porphyrin synthesis

Jackson D. Megiatto, Dustin Patterson, Benjamin D. Sherman, Thomas A Moore, John Devens Gust, Ana L Moore

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A straightforward procedure based on the formation of intramolecular hydrogen bonds to impart selectivity in the preparation of multi-functionalized porphyrins has been developed. To illustrate the concept, the synthesis of a biomimetic artificial photosynthetic model able to undergo electron and proton transfer reactions upon irradiation is reported.

Original languageEnglish
Pages (from-to)4558-4560
Number of pages3
JournalChemical Communications
Volume48
Issue number38
DOIs
Publication statusPublished - May 14 2012

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Proton transfer
Porphyrins
Biomimetics
Hydrogen bonds
Irradiation
Acids
Electrons

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Intramolecular hydrogen bonding as a synthetic tool to induce chemical selectivity in acid catalyzed porphyrin synthesis. / Megiatto, Jackson D.; Patterson, Dustin; Sherman, Benjamin D.; Moore, Thomas A; Gust, John Devens; Moore, Ana L.

In: Chemical Communications, Vol. 48, No. 38, 14.05.2012, p. 4558-4560.

Research output: Contribution to journalArticle

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