Intriguing transport dynamics of ethylammonium nitrate-acetonitrile binary mixtures arising from nano-inhomogeneity

Alessandro Mariani, Matteo Bonomo, Boning Wu, Barbara Centrella, Danilo Dini, Ed Castner, Lorenzo Gontrani

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Binary mixtures of ethylammonium nitrate and acetonitrile show interesting properties that originate from the structural and dynamical nano-heterogeneity present in ionic liquids. These effects are most pronounced when the ionic liquid is the minority compound. In this study the transport properties of such mixtures are studied, including viscosity, self-diffusion and conductivity. The results strongly support the presence of structural inhomogeneity and show an interesting composition-dependent behaviour in the mixtures.

Original languageEnglish
Pages (from-to)27212-27220
Number of pages9
JournalPhysical Chemistry Chemical Physics
Volume19
Issue number40
DOIs
Publication statusPublished - Jan 1 2017

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Ionic Liquids
Binary mixtures
binary mixtures
acetonitrile
nitrates
inhomogeneity
minorities
liquids
Transport properties
transport properties
Viscosity
viscosity
conductivity
Chemical analysis
ethylammonium

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Intriguing transport dynamics of ethylammonium nitrate-acetonitrile binary mixtures arising from nano-inhomogeneity. / Mariani, Alessandro; Bonomo, Matteo; Wu, Boning; Centrella, Barbara; Dini, Danilo; Castner, Ed; Gontrani, Lorenzo.

In: Physical Chemistry Chemical Physics, Vol. 19, No. 40, 01.01.2017, p. 27212-27220.

Research output: Contribution to journalArticle

Mariani, Alessandro ; Bonomo, Matteo ; Wu, Boning ; Centrella, Barbara ; Dini, Danilo ; Castner, Ed ; Gontrani, Lorenzo. / Intriguing transport dynamics of ethylammonium nitrate-acetonitrile binary mixtures arising from nano-inhomogeneity. In: Physical Chemistry Chemical Physics. 2017 ; Vol. 19, No. 40. pp. 27212-27220.
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