Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction

Pirmin A. Ulmann, Adam B. Braunschweig, One Sun Lee, Michael J. Wiester, George C Schatz, Chad A. Mirkin

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

This study describes a heteroligated, hemilabile PtII-P,S tweezer coordination complex that combines a chiral Jacobsen-Katsuki Mn III-salen epoxidation catalyst with an amidopyridine receptor, which leads to an inversion of the major epoxide product compared to catalysts without a recognition group.

Original languageEnglish
Pages (from-to)5121-5123
Number of pages3
JournalChemical Communications
Issue number34
DOIs
Publication statusPublished - 2009

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Epoxidation
Catalyst selectivity
Enzymes
Catalysts
Epoxy Compounds
Coordination Complexes
disalicylaldehyde ethylenediamine

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction. / Ulmann, Pirmin A.; Braunschweig, Adam B.; Lee, One Sun; Wiester, Michael J.; Schatz, George C; Mirkin, Chad A.

In: Chemical Communications, No. 34, 2009, p. 5121-5123.

Research output: Contribution to journalArticle

Ulmann, Pirmin A. ; Braunschweig, Adam B. ; Lee, One Sun ; Wiester, Michael J. ; Schatz, George C ; Mirkin, Chad A. / Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction. In: Chemical Communications. 2009 ; No. 34. pp. 5121-5123.
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