Investigation of formally zerovalent Triphos iron complexes

Tufan K. Mukhopadhyay, Russell K. Feller, Francisca N. Rein, Neil J. Henson, Nathan C. Smythe, Ryan J. Trovitch, John C. Gordon

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The reduction of Triphos [PhP(CH2CH2PPh2)2] iron halide complexes has been explored, yielding formally zerovalent (κ3-Triphos)Fe(κ2-Triphos) and (κ3-Triphos)Fe(κ2-Bpy). Electrochemical analysis, coupled with the metrical parameters of (κ3-Triphos)Fe(κ2-Bpy), reveal an electronic structure consistent with a π-radical monoanion bipyridine chelate that is antiferromagnetically coupled to a low spin, Fe(i) metal center.

Original languageEnglish
Pages (from-to)8670-8672
Number of pages3
JournalChemical Communications
Volume48
Issue number69
DOIs
Publication statusPublished - Aug 1 2012

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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  • Cite this

    Mukhopadhyay, T. K., Feller, R. K., Rein, F. N., Henson, N. J., Smythe, N. C., Trovitch, R. J., & Gordon, J. C. (2012). Investigation of formally zerovalent Triphos iron complexes. Chemical Communications, 48(69), 8670-8672. https://doi.org/10.1039/c2cc33926a