Abstract
The reduction of Triphos [PhP(CH2CH2PPh2)2] iron halide complexes has been explored, yielding formally zerovalent (κ3-Triphos)Fe(κ2-Triphos) and (κ3-Triphos)Fe(κ2-Bpy). Electrochemical analysis, coupled with the metrical parameters of (κ3-Triphos)Fe(κ2-Bpy), reveal an electronic structure consistent with a π-radical monoanion bipyridine chelate that is antiferromagnetically coupled to a low spin, Fe(i) metal center.
Original language | English |
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Pages (from-to) | 8670-8672 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 48 |
Issue number | 69 |
DOIs | |
Publication status | Published - Aug 1 2012 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry