Investigation of formally zerovalent Triphos iron complexes

Tufan K. Mukhopadhyay, Russell K. Feller, Francisca N. Rein, Neil J. Henson, Nathan C. Smythe, Ryan Trovitch, John C. Gordon

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The reduction of Triphos [PhP(CH2CH2PPh 2)2] iron halide complexes has been explored, yielding formally zerovalent (κ3-Triphos)Fe(κ2-Triphos) and (κ3-Triphos)Fe(κ2-Bpy). Electrochemical analysis, coupled with the metrical parameters of (κ3-Triphos) Fe(κ2-Bpy), reveal an electronic structure consistent with a π-radical monoanion bipyridine chelate that is antiferromagnetically coupled to a low spin, Fe(i) metal center.

Original languageEnglish
Pages (from-to)8670-8672
Number of pages3
JournalChemical Communications
Volume48
Issue number69
DOIs
Publication statusPublished - Sep 7 2012

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Electronic structure
Iron
Metals

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Mukhopadhyay, T. K., Feller, R. K., Rein, F. N., Henson, N. J., Smythe, N. C., Trovitch, R., & Gordon, J. C. (2012). Investigation of formally zerovalent Triphos iron complexes. Chemical Communications, 48(69), 8670-8672. https://doi.org/10.1039/c2cc33926a

Investigation of formally zerovalent Triphos iron complexes. / Mukhopadhyay, Tufan K.; Feller, Russell K.; Rein, Francisca N.; Henson, Neil J.; Smythe, Nathan C.; Trovitch, Ryan; Gordon, John C.

In: Chemical Communications, Vol. 48, No. 69, 07.09.2012, p. 8670-8672.

Research output: Contribution to journalArticle

Mukhopadhyay, TK, Feller, RK, Rein, FN, Henson, NJ, Smythe, NC, Trovitch, R & Gordon, JC 2012, 'Investigation of formally zerovalent Triphos iron complexes', Chemical Communications, vol. 48, no. 69, pp. 8670-8672. https://doi.org/10.1039/c2cc33926a
Mukhopadhyay TK, Feller RK, Rein FN, Henson NJ, Smythe NC, Trovitch R et al. Investigation of formally zerovalent Triphos iron complexes. Chemical Communications. 2012 Sep 7;48(69):8670-8672. https://doi.org/10.1039/c2cc33926a
Mukhopadhyay, Tufan K. ; Feller, Russell K. ; Rein, Francisca N. ; Henson, Neil J. ; Smythe, Nathan C. ; Trovitch, Ryan ; Gordon, John C. / Investigation of formally zerovalent Triphos iron complexes. In: Chemical Communications. 2012 ; Vol. 48, No. 69. pp. 8670-8672.
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