Investigation of the hydroformylation of ethylene in liquid carbon dioxide

Clement R. Yonker, John Linehan

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

In situ, high-pressure NMR was used to investigate the hydroformylation reaction of ethylene in liquid CO2 using Rh(CO)2acac as the catalyst precursor and (p-CF3C6H4)3P, tris(p-trifluoromethylphenyl)phosphine, as the ligand under different thermodynamic conditions (T = 10-23 C, PCO = PH2 = 10-15 bar, PC2H4 = 10-15 bar, PCO2 = 207 bar). 1H-NMR was used to monitor the reaction progress of the hydroformylation of ethylene with a rhodium catalyst under select conditions of temperature and CO2 solvent pressure. Potential resting states of the rhodium catalyst were investigated by 31P(1H)-NMR. This is the first description of a rhodium catalyzed hydroformylation reaction in liquid CO2 monitored in situ by high pressure NMR.

Original languageEnglish
Pages (from-to)249-257
Number of pages9
JournalJournal of Organometallic Chemistry
Volume650
Issue number1-2
DOIs
Publication statusPublished - May 1 2002

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Keywords

  • Carbon dioxide
  • Ethylene
  • High presure NMR
  • Hydroformylation
  • Rhodium

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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