Investigation of volatile liquid surfaces by synchrotron x-ray spectroscopy of liquid microjets

Kevin R. Wilson, Bruce S. Rude, Jared Smith, Chris Cappa, Dick T Co, Richard D Schaller, M. Larsson, T. Catalano, R. J. Saykally

Research output: Contribution to journalArticle

90 Citations (Scopus)

Abstract

The development of x-ray absorption spectroscopy (XAS) for the study of volatile liquid surfaces using microjets was discussed. The design and implementation of x-ray experiment based on the use of liquid microjets were described. The experiments characterizing the temperature of liquid water and methanol streams injected into high vacuum through microjet nozzles were analyzed. It was shown that the application of high-vacuum XAS techniques to liquid microjets allows a particular class of measurements to be performed on volatile liquid surfaces without significant interference from the equilibrium vapor.

Original languageEnglish
Pages (from-to)725-736
Number of pages12
JournalReview of Scientific Instruments
Volume75
Issue number3
DOIs
Publication statusPublished - Mar 2004

Fingerprint

liquid surfaces
Synchrotrons
x ray spectroscopy
synchrotrons
Spectroscopy
high vacuum
x ray absorption
X rays
absorption spectroscopy
Liquids
liquids
Absorption spectroscopy
nozzles
Vacuum
methyl alcohol
vapors
interference
Nozzles
Methanol
water

ASJC Scopus subject areas

  • Instrumentation
  • Physics and Astronomy (miscellaneous)

Cite this

Investigation of volatile liquid surfaces by synchrotron x-ray spectroscopy of liquid microjets. / Wilson, Kevin R.; Rude, Bruce S.; Smith, Jared; Cappa, Chris; Co, Dick T; Schaller, Richard D; Larsson, M.; Catalano, T.; Saykally, R. J.

In: Review of Scientific Instruments, Vol. 75, No. 3, 03.2004, p. 725-736.

Research output: Contribution to journalArticle

Wilson, KR, Rude, BS, Smith, J, Cappa, C, Co, DT, Schaller, RD, Larsson, M, Catalano, T & Saykally, RJ 2004, 'Investigation of volatile liquid surfaces by synchrotron x-ray spectroscopy of liquid microjets', Review of Scientific Instruments, vol. 75, no. 3, pp. 725-736. https://doi.org/10.1063/1.1645656
Wilson, Kevin R. ; Rude, Bruce S. ; Smith, Jared ; Cappa, Chris ; Co, Dick T ; Schaller, Richard D ; Larsson, M. ; Catalano, T. ; Saykally, R. J. / Investigation of volatile liquid surfaces by synchrotron x-ray spectroscopy of liquid microjets. In: Review of Scientific Instruments. 2004 ; Vol. 75, No. 3. pp. 725-736.
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