Involvement of a binuclear species with the Re-C(O)O-Re moiety in CO 2 reduction catalyzed by tricarbonyl rhenium(I) complexes with diimine ligands: Strikingly slow formation of the Re-Re and Re-C(O)O-re species from Re(dmb)(CO)3S (dmb = 4,4′-dimethyl-2,2′-bipyridine, S = solvent)

Yukiko Hayashi, Shouichi Kita, Bruce S. Brunschwig, Etsuko Fujita

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